A non-linear phenomenon observed in the photochromic crystals of a rhodium dithionite complex with n -propyl moieties

Hidetaka Nakai; Seiya Miyata; Yuu Kajiwara; Yoshiki Ozawa; Masaaki Abe

doi:10.1039/c9dt04760c

A non-linear phenomenon observed in the photochromic crystals of a rhodium dithionite complex with n -propyl moieties

Hidetaka Nakai, Seiya Miyata, Yuu Kajiwara, Yoshiki Ozawa, Masaaki Abe

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Crystalline-state photochromism of a rhodium dithionite complex with n-propyl moieties was studied directly by performing single crystal X-ray diffraction experiments; a non-linear relationship between the degree of the conformational change of the n-propyl moiety and the degree of the photochromic reaction of the dithionite group (μ-O₂SSO₂) was observed at -173 °C.

Original language	English
Pages (from-to)	1721-1725
Number of pages	5
Journal	Dalton Transactions
Volume	49
Issue number	6
DOIs	https://doi.org/10.1039/c9dt04760c
Publication status	Published - Feb 14 2020
Externally published	Yes

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/c9dt04760c

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title = "A non-linear phenomenon observed in the photochromic crystals of a rhodium dithionite complex with n -propyl moieties",

abstract = "Crystalline-state photochromism of a rhodium dithionite complex with n-propyl moieties was studied directly by performing single crystal X-ray diffraction experiments; a non-linear relationship between the degree of the conformational change of the n-propyl moiety and the degree of the photochromic reaction of the dithionite group (μ-O2SSO2) was observed at -173 °C.",

author = "Hidetaka Nakai and Seiya Miyata and Yuu Kajiwara and Yoshiki Ozawa and Masaaki Abe",

note = "Funding Information: This work was supported by JSPS KAKENHI Grant Numbers JP17K05818, JP17H05387 (Coordination Asymmetry) and JP16H06514 (Coordination Asymmetry) and by the MEXT-supported Program for the Strategic Research Foundation at Private Universities 2014–2018, subsidy from MEXT and Kindai University. Publisher Copyright: {\textcopyright} 2020 The Royal Society of Chemistry.",

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doi = "10.1039/c9dt04760c",

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T1 - A non-linear phenomenon observed in the photochromic crystals of a rhodium dithionite complex with n -propyl moieties

AU - Nakai, Hidetaka

AU - Miyata, Seiya

AU - Kajiwara, Yuu

AU - Ozawa, Yoshiki

AU - Abe, Masaaki

N1 - Funding Information: This work was supported by JSPS KAKENHI Grant Numbers JP17K05818, JP17H05387 (Coordination Asymmetry) and JP16H06514 (Coordination Asymmetry) and by the MEXT-supported Program for the Strategic Research Foundation at Private Universities 2014–2018, subsidy from MEXT and Kindai University. Publisher Copyright: © 2020 The Royal Society of Chemistry.

PY - 2020/2/14

Y1 - 2020/2/14

N2 - Crystalline-state photochromism of a rhodium dithionite complex with n-propyl moieties was studied directly by performing single crystal X-ray diffraction experiments; a non-linear relationship between the degree of the conformational change of the n-propyl moiety and the degree of the photochromic reaction of the dithionite group (μ-O2SSO2) was observed at -173 °C.

AB - Crystalline-state photochromism of a rhodium dithionite complex with n-propyl moieties was studied directly by performing single crystal X-ray diffraction experiments; a non-linear relationship between the degree of the conformational change of the n-propyl moiety and the degree of the photochromic reaction of the dithionite group (μ-O2SSO2) was observed at -173 °C.

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A non-linear phenomenon observed in the photochromic crystals of a rhodium dithionite complex with n -propyl moieties

Abstract

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