A non-linear phenomenon observed in the photochromic crystals of a rhodium dithionite complex with n -propyl moieties

Hidetaka Nakai, Seiya Miyata, Yuu Kajiwara, Yoshiki Ozawa, Masaaki Abe

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Crystalline-state photochromism of a rhodium dithionite complex with n-propyl moieties was studied directly by performing single crystal X-ray diffraction experiments; a non-linear relationship between the degree of the conformational change of the n-propyl moiety and the degree of the photochromic reaction of the dithionite group (μ-O2SSO2) was observed at -173 °C.

Original languageEnglish
Pages (from-to)1721-1725
Number of pages5
JournalDalton Transactions
Volume49
Issue number6
DOIs
Publication statusPublished - Feb 14 2020
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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