A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H2salabza: N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)3]

Miwa Sasaki, Hiroaki Horiuchi, Motoko Kumagai, Masatomi Sakamoto, Hiroshi Sakiyama, Yuzo Nishida, Yoshihiko Sadaoka, Masaaki Ohba, Hisashi Okawa

Research output: Contribution to journal › Article

22 Citations (Scopus)

Abstract

Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)3], was synthesized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)3]·2H2O, where H2salabza and Hhfac denote N,N′-bis(salicylidene)-2-amino-benzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectively. Structural analysis revealed that the complex has the long intermolecular metal-metal distances enough to be regarded as a discrete one.

Original languageEnglish
Pages (from-to)911-912
Number of pages2
JournalChemistry Letters
Issue number9
DOIs
Publication statusPublished - Jan 1 1998

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Metals
Structural analysis
benzylamine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H2salabza : N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)3]. / Sasaki, Miwa; Horiuchi, Hiroaki; Kumagai, Motoko; Sakamoto, Masatomi; Sakiyama, Hiroshi; Nishida, Yuzo; Sadaoka, Yoshihiko; Ohba, Masaaki; Okawa, Hisashi.

In: Chemistry Letters, No. 9, 01.01.1998, p. 911-912.

Research output: Contribution to journal › Article

Sasaki, M, Horiuchi, H, Kumagai, M, Sakamoto, M, Sakiyama, H, Nishida, Y, Sadaoka, Y, Ohba, M & Okawa, H 1998, 'A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H2salabza: N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)3]', Chemistry Letters, no. 9, pp. 911-912. https://doi.org/10.1246/cl.1998.911
Sasaki M, Horiuchi H, Kumagai M, Sakamoto M, Sakiyama H, Nishida Y et al. A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H2salabza: N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)3]. Chemistry Letters. 1998 Jan 1;(9):911-912. https://doi.org/10.1246/cl.1998.911
Sasaki, Miwa ; Horiuchi, Hiroaki ; Kumagai, Motoko ; Sakamoto, Masatomi ; Sakiyama, Hiroshi ; Nishida, Yuzo ; Sadaoka, Yoshihiko ; Ohba, Masaaki ; Okawa, Hisashi. / A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H2salabza : N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)3]. In: Chemistry Letters. 1998 ; No. 9. pp. 911-912.
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AB - Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)3], was synthesized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)3]·2H2O, where H2salabza and Hhfac denote N,N′-bis(salicylidene)-2-amino-benzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectively. Structural analysis revealed that the complex has the long intermolecular metal-metal distances enough to be regarded as a discrete one.

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