A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H2salabza: N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)3]

Miwa Sasaki, Hiroaki Horiuchi, Motoko Kumagai, Masatomi Sakamoto, Hiroshi Sakiyama, Yuzo Nishida, Yoshihiko Sadaoka, Masaaki Ohba, Hisashi Okawa

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Abstract

Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)3], was synthesized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)3]·2H2O, where H2salabza and Hhfac denote N,N′-bis(salicylidene)-2-amino-benzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectively. Structural analysis revealed that the complex has the long intermolecular metal-metal distances enough to be regarded as a discrete one.

Original languageEnglish
Pages (from-to)911-912
Number of pages2
JournalChemistry Letters
Issue number9
DOIs
Publication statusPublished - Jan 1 1998

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Metals
Structural analysis
benzylamine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H2salabza : N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)3]. / Sasaki, Miwa; Horiuchi, Hiroaki; Kumagai, Motoko; Sakamoto, Masatomi; Sakiyama, Hiroshi; Nishida, Yuzo; Sadaoka, Yoshihiko; Ohba, Masaaki; Okawa, Hisashi.

In: Chemistry Letters, No. 9, 01.01.1998, p. 911-912.

Research output: Contribution to journalArticle

Sasaki, Miwa ; Horiuchi, Hiroaki ; Kumagai, Motoko ; Sakamoto, Masatomi ; Sakiyama, Hiroshi ; Nishida, Yuzo ; Sadaoka, Yoshihiko ; Ohba, Masaaki ; Okawa, Hisashi. / A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H2salabza : N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)3]. In: Chemistry Letters. 1998 ; No. 9. pp. 911-912.
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abstract = "Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)3], was synthesized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)3]·2H2O, where H2salabza and Hhfac denote N,N′-bis(salicylidene)-2-amino-benzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectively. Structural analysis revealed that the complex has the long intermolecular metal-metal distances enough to be regarded as a discrete one.",
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AU - Sakiyama, Hiroshi

AU - Nishida, Yuzo

AU - Sadaoka, Yoshihiko

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