A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H2salabza: N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)3]

Miwa Sasaki; Hiroaki Horiuchi; Motoko Kumagai; Masatomi Sakamoto; Hiroshi Sakiyama; Yuzo Nishida; Yoshihiko Sadaoka; Masaaki Ohba; Hisashi Okawa

doi:10.1246/cl.1998.911

A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H₂salabza: N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)₃]

Miwa Sasaki, Hiroaki Horiuchi, Motoko Kumagai, Masatomi Sakamoto, Hiroshi Sakiyama, Yuzo Nishida, Yoshihiko Sadaoka, Masaaki Ohba, Hisashi Okawa

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)₃], was synthesized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)₃]·2H₂O, where H₂salabza and Hhfac denote N,N′-bis(salicylidene)-2-amino-benzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectively. Structural analysis revealed that the complex has the long intermolecular metal-metal distances enough to be regarded as a discrete one.

Original language	English
Pages (from-to)	911-912
Number of pages	2
Journal	Chemistry Letters
Issue number	9
DOIs	https://doi.org/10.1246/cl.1998.911
Publication status	Published - Jan 1 1998

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.1998.911

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A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H₂salabza : N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)₃]. / Sasaki, Miwa; Horiuchi, Hiroaki; Kumagai, Motoko; Sakamoto, Masatomi; Sakiyama, Hiroshi; Nishida, Yuzo; Sadaoka, Yoshihiko; Ohba, Masaaki; Okawa, Hisashi.

In: Chemistry Letters, No. 9, 01.01.1998, p. 911-912.

Research output: Contribution to journal › Article › peer-review

Sasaki, Miwa ; Horiuchi, Hiroaki ; Kumagai, Motoko ; Sakamoto, Masatomi ; Sakiyama, Hiroshi ; Nishida, Yuzo ; Sadaoka, Yoshihiko ; Ohba, Masaaki ; Okawa, Hisashi. / A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H₂salabza : N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)₃]. In: Chemistry Letters. 1998 ; No. 9. pp. 911-912.

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title = "A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H2salabza: N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)3]",

abstract = "Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)3], was synthesized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)3]·2H2O, where H2salabza and Hhfac denote N,N′-bis(salicylidene)-2-amino-benzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectively. Structural analysis revealed that the complex has the long intermolecular metal-metal distances enough to be regarded as a discrete one.",

author = "Miwa Sasaki and Hiroaki Horiuchi and Motoko Kumagai and Masatomi Sakamoto and Hiroshi Sakiyama and Yuzo Nishida and Yoshihiko Sadaoka and Masaaki Ohba and Hisashi Okawa",

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AU - Sasaki, Miwa

AU - Horiuchi, Hiroaki

AU - Kumagai, Motoko

AU - Sakamoto, Masatomi

AU - Sakiyama, Hiroshi

AU - Nishida, Yuzo

AU - Sadaoka, Yoshihiko

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AU - Okawa, Hisashi

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AB - Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)3], was synthesized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)3]·2H2O, where H2salabza and Hhfac denote N,N′-bis(salicylidene)-2-amino-benzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectively. Structural analysis revealed that the complex has the long intermolecular metal-metal distances enough to be regarded as a discrete one.

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