TY - JOUR
T1 - A novel discrete d-f heterobinuclear complex designed from tetrahedrally distorted [Cu(salabza)] (H2salabza
T2 - N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)3]
AU - Sasaki, Miwa
AU - Horiuchi, Hiroaki
AU - Kumagai, Motoko
AU - Sakamoto, Masatomi
AU - Sakiyama, Hiroshi
AU - Nishida, Yuzo
AU - Sadaoka, Yoshihiko
AU - Ohba, Masaaki
AU - Okawa, Hisashi
PY - 1998/1/1
Y1 - 1998/1/1
N2 - Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)3], was synthesized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)3]·2H2O, where H2salabza and Hhfac denote N,N′-bis(salicylidene)-2-amino-benzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectively. Structural analysis revealed that the complex has the long intermolecular metal-metal distances enough to be regarded as a discrete one.
AB - Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)3], was synthesized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)3]·2H2O, where H2salabza and Hhfac denote N,N′-bis(salicylidene)-2-amino-benzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectively. Structural analysis revealed that the complex has the long intermolecular metal-metal distances enough to be regarded as a discrete one.
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U2 - 10.1246/cl.1998.911
DO - 10.1246/cl.1998.911
M3 - Article
AN - SCOPUS:0032358084
SP - 911
EP - 912
JO - Chemistry Letters
JF - Chemistry Letters
SN - 0366-7022
IS - 9
ER -