A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni-azide circles and an in situ cyanomethylated di-2-pyridyl ketone

Ming Liang Tong; Montserrat Monfort; Juan Modesto Clemente Juan; Xiao Ming Chen; Xian He Bu; Masaaki Ohba; Susumu Kitagawa

doi:10.1039/b415431b

A novel high-spin heterometallic Ni₁₂K₄ cluster incorporating large Ni-azide circles and an in situ cyanomethylated di-2-pyridyl ketone

Ming Liang Tong, Montserrat Monfort, Juan Modesto Clemente Juan, Xiao Ming Chen, Xian He Bu, Masaaki Ohba, Susumu Kitagawa

Research output: Contribution to journal › Article › peer-review

90 Citations (Scopus)

Abstract

Reaction of di-2-pyridyl ketone (dpk) with nickel acetate and azide in the presence of potassium tert-butylate as a catalytic base generates the title compound, which contains the largest [Ni(μ_1,1-N₃)] ₆ circles in the discrete ferromagnetically-coupled M ^II-azide cluster family, and shows an unprecedented in situ cyanomethylation of ketone.

Original language	English
Pages (from-to)	233-235
Number of pages	3
Journal	Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/b415431b
Publication status	Published - Jan 14 2005
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b415431b

Cite this

@article{02a12401a2b74640bf0957b9406d8187,

title = "A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni-azide circles and an in situ cyanomethylated di-2-pyridyl ketone",

abstract = "Reaction of di-2-pyridyl ketone (dpk) with nickel acetate and azide in the presence of potassium tert-butylate as a catalytic base generates the title compound, which contains the largest [Ni(μ1,1-N3)] 6 circles in the discrete ferromagnetically-coupled M II-azide cluster family, and shows an unprecedented in situ cyanomethylation of ketone.",

author = "Tong, {Ming Liang} and Montserrat Monfort and {Clemente Juan}, {Juan Modesto} and Chen, {Xiao Ming} and Bu, {Xian He} and Masaaki Ohba and Susumu Kitagawa",

year = "2005",

month = jan,

day = "14",

doi = "10.1039/b415431b",

language = "English",

pages = "233--235",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni-azide circles and an in situ cyanomethylated di-2-pyridyl ketone

AU - Tong, Ming Liang

AU - Monfort, Montserrat

AU - Clemente Juan, Juan Modesto

AU - Chen, Xiao Ming

AU - Bu, Xian He

AU - Ohba, Masaaki

AU - Kitagawa, Susumu

PY - 2005/1/14

Y1 - 2005/1/14

N2 - Reaction of di-2-pyridyl ketone (dpk) with nickel acetate and azide in the presence of potassium tert-butylate as a catalytic base generates the title compound, which contains the largest [Ni(μ1,1-N3)] 6 circles in the discrete ferromagnetically-coupled M II-azide cluster family, and shows an unprecedented in situ cyanomethylation of ketone.

AB - Reaction of di-2-pyridyl ketone (dpk) with nickel acetate and azide in the presence of potassium tert-butylate as a catalytic base generates the title compound, which contains the largest [Ni(μ1,1-N3)] 6 circles in the discrete ferromagnetically-coupled M II-azide cluster family, and shows an unprecedented in situ cyanomethylation of ketone.

UR - http://www.scopus.com/inward/record.url?scp=12844264786&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=12844264786&partnerID=8YFLogxK

U2 - 10.1039/b415431b

DO - 10.1039/b415431b

M3 - Article

AN - SCOPUS:12844264786

SN - 1359-7345

SP - 233

EP - 235

JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

A novel high-spin heterometallic Ni₁₂K₄ cluster incorporating large Ni-azide circles and an in situ cyanomethylated di-2-pyridyl ketone

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this