A novel LIESST iron(II) complex exhibiting a high relaxation temperature

S. Hayami, Z. Z. Gu, Y. Einaga, Y. Kobayasi, Y. Ishikawa, Y. Yamada, A. Fujishima, Osamu Sato

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Abstract

The spin-crossover iron(II) complex [Fe(L)(CN)2·H2O (1) has been investigated. Complex 1 has a pentagonal bipyramidal structure which is seven-coordinated, containing an N3O2 macrocycle and two CN- ligands. Water molecules bind the complex by means of hydrogen bonding. It was found that the complex 1 exhibited a light-induced excited spin state trapping (LIESST) effect. The relaxation temperature is above 130 K, which is the highest temperature for LIESST compounds reported so far.

Original languageEnglish
Pages (from-to)3240-3242
Number of pages3
JournalInorganic Chemistry
Volume40
Issue number13
DOIs
Publication statusPublished - Jun 18 2001
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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    Hayami, S., Gu, Z. Z., Einaga, Y., Kobayasi, Y., Ishikawa, Y., Yamada, Y., Fujishima, A., & Sato, O. (2001). A novel LIESST iron(II) complex exhibiting a high relaxation temperature. Inorganic Chemistry, 40(13), 3240-3242. https://doi.org/10.1021/ic000708e