A novel tetranuclear iron(III) complex having L-alanine bridges and an unprecedented (Fe4(O2H)) Core

Shigenobu Yano, Tomoko Inagaki, Yasuko Yamada, Masako Kato, Mikio Yamasaki, Ken Sakai, Taro Tsubomura, Mitsunobu Sato, Wasuke Mori, Kazuya Yamaguchi, Isamu Kinoshita

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Abstract

The reaction of L-alanine (L-ala) with Fe(NO3)2·9H2O in the presence of H5dhpta (1,3-diamino-2-hydroxypropaneN,N,N′,N′-tetraacetic acid) and base (NaOH) affords the novel tetranuclear complex Na[Fe4(dhpta)2(O)(OH)(L-ala)2]·6H 2O having L-alaninato bridges and an (Fe4(O2H))9+ core whose crystal structure and magnetic properties were determined.

Original languageEnglish
Pages (from-to)61-62
Number of pages2
JournalChemistry Letters
Issue number1
DOIs
Publication statusPublished - Jan 1 1996
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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