A novel tetranuclear iron(III) complex having L-alanine bridges and an unprecedented (Fe4(O2H)) Core

Shigenobu Yano; Tomoko Inagaki; Yasuko Yamada; Masako Kato; Mikio Yamasaki; Ken Sakai; Taro Tsubomura; Mitsunobu Sato; Wasuke Mori; Kazuya Yamaguchi; Isamu Kinoshita

doi:10.1246/cl.1996.61

A novel tetranuclear iron(III) complex having L-alanine bridges and an unprecedented (Fe₄(O₂H)) Core

Shigenobu Yano, Tomoko Inagaki, Yasuko Yamada, Masako Kato, Mikio Yamasaki, Ken Sakai, Taro Tsubomura, Mitsunobu Sato, Wasuke Mori, Kazuya Yamaguchi, Isamu Kinoshita

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The reaction of L-alanine (L-ala) with Fe(NO₃)₂·9H₂O in the presence of H₅dhpta (1,3-diamino-2-hydroxypropaneN,N,N′,N′-tetraacetic acid) and base (NaOH) affords the novel tetranuclear complex Na[Fe₄(dhpta)₂(O)(OH)(L-ala)₂]·6H ₂O having L-alaninato bridges and an (Fe₄(O₂H))⁹⁺ core whose crystal structure and magnetic properties were determined.

Original language	English
Pages (from-to)	61-62
Number of pages	2
Journal	Chemistry Letters
Issue number	1
DOIs	https://doi.org/10.1246/cl.1996.61
Publication status	Published - Jan 1 1996
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.1996.61

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title = "A novel tetranuclear iron(III) complex having L-alanine bridges and an unprecedented (Fe4(O2H)) Core",

abstract = "The reaction of L-alanine (L-ala) with Fe(NO3)2·9H2O in the presence of H5dhpta (1,3-diamino-2-hydroxypropaneN,N,N′,N′-tetraacetic acid) and base (NaOH) affords the novel tetranuclear complex Na[Fe4(dhpta)2(O)(OH)(L-ala)2]·6H 2O having L-alaninato bridges and an (Fe4(O2H))9+ core whose crystal structure and magnetic properties were determined.",

author = "Shigenobu Yano and Tomoko Inagaki and Yasuko Yamada and Masako Kato and Mikio Yamasaki and Ken Sakai and Taro Tsubomura and Mitsunobu Sato and Wasuke Mori and Kazuya Yamaguchi and Isamu Kinoshita",

year = "1996",

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doi = "10.1246/cl.1996.61",

language = "English",

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journal = "Chemistry Letters",

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T1 - A novel tetranuclear iron(III) complex having L-alanine bridges and an unprecedented (Fe4(O2H)) Core

AU - Yano, Shigenobu

AU - Inagaki, Tomoko

AU - Yamada, Yasuko

AU - Kato, Masako

AU - Yamasaki, Mikio

AU - Sakai, Ken

AU - Tsubomura, Taro

AU - Sato, Mitsunobu

AU - Mori, Wasuke

AU - Yamaguchi, Kazuya

AU - Kinoshita, Isamu

PY - 1996/1/1

Y1 - 1996/1/1

N2 - The reaction of L-alanine (L-ala) with Fe(NO3)2·9H2O in the presence of H5dhpta (1,3-diamino-2-hydroxypropaneN,N,N′,N′-tetraacetic acid) and base (NaOH) affords the novel tetranuclear complex Na[Fe4(dhpta)2(O)(OH)(L-ala)2]·6H 2O having L-alaninato bridges and an (Fe4(O2H))9+ core whose crystal structure and magnetic properties were determined.

AB - The reaction of L-alanine (L-ala) with Fe(NO3)2·9H2O in the presence of H5dhpta (1,3-diamino-2-hydroxypropaneN,N,N′,N′-tetraacetic acid) and base (NaOH) affords the novel tetranuclear complex Na[Fe4(dhpta)2(O)(OH)(L-ala)2]·6H 2O having L-alaninato bridges and an (Fe4(O2H))9+ core whose crystal structure and magnetic properties were determined.

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DO - 10.1246/cl.1996.61

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JO - Chemistry Letters

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SN - 0366-7022

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A novel tetranuclear iron(III) complex having L-alanine bridges and an unprecedented (Fe₄(O₂H)) Core

Abstract

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