A novel tetranuclear iron(III) complex having L-alanine bridges and an unprecedented (Fe4(O2H)) Core

Shigenobu Yano, Tomoko Inagaki, Yasuko Yamada, Masako Kato, Mikio Yamasaki, Ken Sakai, Taro Tsubomura, Mitsunobu Sato, Wasuke Mori, Kazuya Yamaguchi, Isamu Kinoshita

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

The reaction of L-alanine (L-ala) with Fe(NO3)2·9H2O in the presence of H5dhpta (1,3-diamino-2-hydroxypropaneN,N,N′,N′-tetraacetic acid) and base (NaOH) affords the novel tetranuclear complex Na[Fe4(dhpta)2(O)(OH)(L-ala)2]·6H 2O having L-alaninato bridges and an (Fe4(O2H))9+ core whose crystal structure and magnetic properties were determined.

Original languageEnglish
Pages (from-to)61-62
Number of pages2
JournalChemistry Letters
Issue number1
DOIs
Publication statusPublished - Jan 1 1996
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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