A one-dimensional homochiral Mo(iv)-Cu(ii) coordination polymer: Spontaneous resolution and photoresponsive properties

Wen Zhang, Hao Ling Sun, Osamu Sato

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

A one-dimensional homochiral MoIVCuII compound, [Cu(tren)][Cu(33)][Mo(CN)8]·4H2O (1, tren = tris(2-aminoethyl)amine, 33 = bis(3-aminopropyl)amine), was synthesized and characterized. Compound 1 experiences spontaneous resolution from achiral components and crystallized in a chiral space group P21. It exhibits photomagnetism via photoinduced metal-to-metal charge transfer, making it a novel example of multifunctional molecule-based materials.

Original languageEnglish
Pages (from-to)4045-4047
Number of pages3
JournalCrystEngComm
Volume12
Issue number12
DOIs
Publication statusPublished - Dec 1 2010

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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