A palladium-catalyzed addition reaction of aroyl/heteroaroyl acid anhydrides to norbornenes

Mieko Arisawa; Saori Tanii; Masahiko Yamaguchi

doi:10.1039/c4cc07759h

A palladium-catalyzed addition reaction of aroyl/heteroaroyl acid anhydrides to norbornenes

Mieko Arisawa, Saori Tanii, Masahiko Yamaguchi

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A palladium complex derived from Pd₂(dba)₃ and dppp catalyzes the addition reaction of aroyl/heteroaroyl acid anhydrides to norbornenes, giving 2-aroyl/heteroaroyl-3-aroyloxy/heteroaroyloxy-bicyclo[2,2,1]heptanes. The C-O bond of acid anhydride is cleaved, and the aroyl/heteroaroyl and aroyloxy/heteroaroyloxy groups are added to alkenes. trans-Adducts are selectively obtained with the endo-benzoyl group and exo-benzoyloxy group.

Original language	English
Pages (from-to)	15267-15270
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	96
DOIs	https://doi.org/10.1039/c4cc07759h
Publication status	Published - Nov 6 2014
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c4cc07759h

Cite this

@article{bf07d5f9b99a42469c2143c2b6629fb7,

title = "A palladium-catalyzed addition reaction of aroyl/heteroaroyl acid anhydrides to norbornenes",

abstract = "A palladium complex derived from Pd2(dba)3 and dppp catalyzes the addition reaction of aroyl/heteroaroyl acid anhydrides to norbornenes, giving 2-aroyl/heteroaroyl-3-aroyloxy/heteroaroyloxy-bicyclo[2,2,1]heptanes. The C-O bond of acid anhydride is cleaved, and the aroyl/heteroaroyl and aroyloxy/heteroaroyloxy groups are added to alkenes. trans-Adducts are selectively obtained with the endo-benzoyl group and exo-benzoyloxy group.",

author = "Mieko Arisawa and Saori Tanii and Masahiko Yamaguchi",

year = "2014",

month = nov,

day = "6",

doi = "10.1039/c4cc07759h",

language = "English",

volume = "50",

pages = "15267--15270",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "96",

}

TY - JOUR

T1 - A palladium-catalyzed addition reaction of aroyl/heteroaroyl acid anhydrides to norbornenes

AU - Arisawa, Mieko

AU - Tanii, Saori

AU - Yamaguchi, Masahiko

PY - 2014/11/6

Y1 - 2014/11/6

N2 - A palladium complex derived from Pd2(dba)3 and dppp catalyzes the addition reaction of aroyl/heteroaroyl acid anhydrides to norbornenes, giving 2-aroyl/heteroaroyl-3-aroyloxy/heteroaroyloxy-bicyclo[2,2,1]heptanes. The C-O bond of acid anhydride is cleaved, and the aroyl/heteroaroyl and aroyloxy/heteroaroyloxy groups are added to alkenes. trans-Adducts are selectively obtained with the endo-benzoyl group and exo-benzoyloxy group.

AB - A palladium complex derived from Pd2(dba)3 and dppp catalyzes the addition reaction of aroyl/heteroaroyl acid anhydrides to norbornenes, giving 2-aroyl/heteroaroyl-3-aroyloxy/heteroaroyloxy-bicyclo[2,2,1]heptanes. The C-O bond of acid anhydride is cleaved, and the aroyl/heteroaroyl and aroyloxy/heteroaroyloxy groups are added to alkenes. trans-Adducts are selectively obtained with the endo-benzoyl group and exo-benzoyloxy group.

UR - http://www.scopus.com/inward/record.url?scp=84910024210&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84910024210&partnerID=8YFLogxK

U2 - 10.1039/c4cc07759h

DO - 10.1039/c4cc07759h

M3 - Article

C2 - 25347414

AN - SCOPUS:84910024210

SN - 1359-7345

VL - 50

SP - 15267

EP - 15270

JO - Chemical Communications

JF - Chemical Communications

IS - 96

ER -

A palladium-catalyzed addition reaction of aroyl/heteroaroyl acid anhydrides to norbornenes

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this