A palladium-nanoparticle and silicon-nanowire-array hybrid: A platform for catalytic heterogeneous reactions

Yoichi M.A. Yamada, Yoshinari Yuyama, Takuma Sato, Shigenori Fujikawa, Yasuhiro Uozumi

Research output: Contribution to journalArticle

74 Citations (Scopus)

Abstract

We report the development of a silicon nanowire array-stabilized palladium nanoparticle catalyst, SiNA-Pd. Its use in the palladium-catalyzed Mizoroki-Heck reaction, the hydrogenation of an alkene, the hydrogenolysis of nitrobenzene, the hydrosilylation of an α,β-unsaturated ketone, and the C-H bond functionalization reactions of thiophenes and indoles achieved a quantitative production with high reusability. The catalytic activity reached several hundred-mol ppb of palladium, reaching a TON of 2 000 000. An array of reactions: A silicon-nanowire-array-stabilized palladium-nanoparticle catalyst, SiNA-Pd, was designed and used in the palladium-catalyzed Mizoroki-Heck reaction. It can catalyze a variety of other reactions and has a high reusability.

Original languageEnglish
Pages (from-to)127-131
Number of pages5
JournalAngewandte Chemie - International Edition
Volume53
Issue number1
DOIs
Publication statusPublished - Jan 3 2014

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Palladium
Silicon
Nanowires
Nanoparticles
Reusability
Indoles
Hydrosilylation
Thiophenes
Hydrogenolysis
Catalysts
Nitrobenzene
Alkenes
Thiophene
Ketones
Olefins
Hydrogenation
Catalyst activity

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

A palladium-nanoparticle and silicon-nanowire-array hybrid : A platform for catalytic heterogeneous reactions. / Yamada, Yoichi M.A.; Yuyama, Yoshinari; Sato, Takuma; Fujikawa, Shigenori; Uozumi, Yasuhiro.

In: Angewandte Chemie - International Edition, Vol. 53, No. 1, 03.01.2014, p. 127-131.

Research output: Contribution to journalArticle

Yamada, Yoichi M.A. ; Yuyama, Yoshinari ; Sato, Takuma ; Fujikawa, Shigenori ; Uozumi, Yasuhiro. / A palladium-nanoparticle and silicon-nanowire-array hybrid : A platform for catalytic heterogeneous reactions. In: Angewandte Chemie - International Edition. 2014 ; Vol. 53, No. 1. pp. 127-131.
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