A robust symmetrical electrode with layered perovskite structure for direct hydrocarbon solid oxide fuel cells: PrBa0.8Ca0.2Mn2O5+δ

S. Choi, S. Sengodan, S. Park, Y. W. Ju, J. Kim, J. Hyodo, H. Y. Jeong, T. Ishihara, J. Shin, G. Kim

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52 Citations (Scopus)

Abstract

Symmetrical solid oxide fuel cells (SOFCs), where the same material is used as both the anode and the cathode, have gained increasing attention due to a number of attractive benefits compared to the conventional SOFC such as a simplified fabrication procedure, reduced processing costs, minimized compatibility issues, as well as enhanced stability and reliability. Since the anode is in a reducing environment while the cathode is in an oxidizing environment, the symmetrical SOFC electrode should be chemically and structurally stable in both environments. Herein, we propose a highly stable symmetrical SOFC electrode, a layered perovskite Ca doped PrBaMn2O5+δ (PBCMO). The electrical conductivity of this electrode is very high in a reducing atmosphere and suitable in an oxidizing atmosphere. Furthermore, the PBCMO symmetrical electrode demonstrates excellent electrochemical performance and durability in various hydrocarbon fuels as well as hydrogen.

Original languageEnglish
Pages (from-to)1747-1753
Number of pages7
JournalJournal of Materials Chemistry A
Volume4
Issue number5
DOIs
Publication statusPublished - Feb 7 2016

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

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