Abstract
The scandium sulfonate-based coordination polymer Sc2(BPDS)3, which is easily prepared by mixing scandium triisopropoxides and biphenyl-4,4'-disulfonic acid (BPDSA), is an air-stable and storable solid that effectively catalyzes the Friedel-Crafts reaction of indoles with aromatic aldehydes under heterogeneous conditions to afford various aryl(diindolyl)methanes. The catalyst can be reused without significant loss of activity after separation from the reaction mixture by simple centrifugation followed by drying.
| Original language | English |
|---|---|
| Pages (from-to) | 1473-1481 |
| Number of pages | 9 |
| Journal | Journal of oleo science |
| Volume | 67 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Jan 1 2018 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Chemical Engineering(all)
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A Scandium Arylsulfonate-based Coordination Polymer as a Heterogeneous Catalyst for the Friedel-Crafts Reaction of Indoles with Aldehydes. / Tungjiratthitikan, Pennapa; Furuno, Hiroshi.
In: Journal of oleo science, Vol. 67, No. 11, 01.01.2018, p. 1473-1481.Research output: Contribution to journal › Article
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TY - JOUR
T1 - A Scandium Arylsulfonate-based Coordination Polymer as a Heterogeneous Catalyst for the Friedel-Crafts Reaction of Indoles with Aldehydes
AU - Tungjiratthitikan, Pennapa
AU - Furuno, Hiroshi
PY - 2018/1/1
Y1 - 2018/1/1
N2 - The scandium sulfonate-based coordination polymer Sc2(BPDS)3, which is easily prepared by mixing scandium triisopropoxides and biphenyl-4,4'-disulfonic acid (BPDSA), is an air-stable and storable solid that effectively catalyzes the Friedel-Crafts reaction of indoles with aromatic aldehydes under heterogeneous conditions to afford various aryl(diindolyl)methanes. The catalyst can be reused without significant loss of activity after separation from the reaction mixture by simple centrifugation followed by drying.
AB - The scandium sulfonate-based coordination polymer Sc2(BPDS)3, which is easily prepared by mixing scandium triisopropoxides and biphenyl-4,4'-disulfonic acid (BPDSA), is an air-stable and storable solid that effectively catalyzes the Friedel-Crafts reaction of indoles with aromatic aldehydes under heterogeneous conditions to afford various aryl(diindolyl)methanes. The catalyst can be reused without significant loss of activity after separation from the reaction mixture by simple centrifugation followed by drying.
UR - http://www.scopus.com/inward/record.url?scp=85056423782&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85056423782&partnerID=8YFLogxK
U2 - 10.5650/jos.ess18077
DO - 10.5650/jos.ess18077
M3 - Article
C2 - 30404968
AN - SCOPUS:85056423782
VL - 67
SP - 1473
EP - 1481
JO - Journal of Oleo Science
JF - Journal of Oleo Science
SN - 1345-8957
IS - 11
ER -