A secondary reagent-assisted synthesis of a novel NiII-Mo IV chiral coordination polymer

Wen Zhang; Zhi Qiang Wang; Osamu Sato; Ren Gen Xiong

doi:10.1021/cg900062y

A secondary reagent-assisted synthesis of a novel Ni^II-Mo ^IV chiral coordination polymer

Wen Zhang, Zhi Qiang Wang, Osamu Sato, Ren Gen Xiong

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

With the aid of a secondary reagent [Cu^II(tren)](ClO ₄)₂, a novel chiral one-dimensional coordination polymer, [Ni^II(tren)]₃[Mo^IV(CN)₈](ClO ₄)₂ -5H₂O (1) (tren ) tris(2-aminoethyl)amine), was inadvertently but reproducibly synthesized, which crystallizes in a chiral space group P2₁2₁2₁ and shows a complex triple-stranded helical structure.

Original language	English
Pages (from-to)	2050-2053
Number of pages	4
Journal	Crystal Growth and Design
Volume	9
Issue number	5
DOIs	https://doi.org/10.1021/cg900062y
Publication status	Published - May 6 2009

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "A secondary reagent-assisted synthesis of a novel NiII-Mo IV chiral coordination polymer",

abstract = "With the aid of a secondary reagent [CuII(tren)](ClO 4)2, a novel chiral one-dimensional coordination polymer, [NiII(tren)]3[MoIV(CN)8](ClO 4)2 -5H2O (1) (tren ) tris(2-aminoethyl)amine), was inadvertently but reproducibly synthesized, which crystallizes in a chiral space group P212121 and shows a complex triple-stranded helical structure.",

author = "Wen Zhang and Wang, {Zhi Qiang} and Osamu Sato and Xiong, {Ren Gen}",

year = "2009",

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AU - Wang, Zhi Qiang

AU - Sato, Osamu

AU - Xiong, Ren Gen

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Y1 - 2009/5/6

N2 - With the aid of a secondary reagent [CuII(tren)](ClO 4)2, a novel chiral one-dimensional coordination polymer, [NiII(tren)]3[MoIV(CN)8](ClO 4)2 -5H2O (1) (tren ) tris(2-aminoethyl)amine), was inadvertently but reproducibly synthesized, which crystallizes in a chiral space group P212121 and shows a complex triple-stranded helical structure.

AB - With the aid of a secondary reagent [CuII(tren)](ClO 4)2, a novel chiral one-dimensional coordination polymer, [NiII(tren)]3[MoIV(CN)8](ClO 4)2 -5H2O (1) (tren ) tris(2-aminoethyl)amine), was inadvertently but reproducibly synthesized, which crystallizes in a chiral space group P212121 and shows a complex triple-stranded helical structure.

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