A solid polymer water electrolysis system utilizing natural circulation

Yoshinori Kobayashi, Kenichiro Kosaka, Takashi Yamamoto, Yuya Tachikawa, Kohei Ito, Kazunari Sasaki

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Solid Polymer Water Electrolysis (SPWE) is a method to efficiently produce high-purity hydrogen gas using a polymer electrolyte membrane-based system. SPWE systems that utilize natural water circulation (resulting from a difference in buoyancy) are a promising technology, which need no additional circulation pump for water supply to the electrolysis cells, and generate no pressure difference between the hydrogen generation and oxygen generation chambers. However, despite not needing an accurate pressure control, gas bubbles formed and trapped within the cell stacks can inhibit heat convection, leading to hot-spot formation and consequent destructive degradation. Improving the reliability is therefore one of the most important technological issues in natural circulation SPWEs. In this study, hot-spot formation is studied both by numerical heat and flow analysis, and by experimental in-situ visualization. This leads to insights into the degradation mechanisms of SPWE stacks, and their possible solutions. An improved design for an SPWE cell stack is successfully fabricated, and reliable operation up to 5000 h is demonstrated.

Original languageEnglish
Pages (from-to)16263-16274
Number of pages12
JournalInternational Journal of Hydrogen Energy
Volume39
Issue number29
DOIs
Publication statusPublished - Oct 2 2014

Fingerprint

electrolysis
Electrolysis
polymers
Polymers
water
Water
cells
water circulation
degradation
Degradation
heat
Heat convection
Hydrogen
Pressure control
hydrogen
Buoyancy
Gases
Water supply
gases
buoyancy

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

Cite this

A solid polymer water electrolysis system utilizing natural circulation. / Kobayashi, Yoshinori; Kosaka, Kenichiro; Yamamoto, Takashi; Tachikawa, Yuya; Ito, Kohei; Sasaki, Kazunari.

In: International Journal of Hydrogen Energy, Vol. 39, No. 29, 02.10.2014, p. 16263-16274.

Research output: Contribution to journalArticle

Kobayashi, Yoshinori ; Kosaka, Kenichiro ; Yamamoto, Takashi ; Tachikawa, Yuya ; Ito, Kohei ; Sasaki, Kazunari. / A solid polymer water electrolysis system utilizing natural circulation. In: International Journal of Hydrogen Energy. 2014 ; Vol. 39, No. 29. pp. 16263-16274.
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