A spin-crossover cluster of iron(II) exhibiting a mixed-spin structure and synergy between spin transition and magnetic interaction

Da Yu Wu, Osamu Sato, Yasuaki Einaga, Chun Ying Duan

Research output: Contribution to journalArticle

144 Citations (Scopus)

Abstract

How low can you go? An Fell4 square was prepared by self-assembly and exhibits both thermally induced and photoinduced spin crossover from a system with four high-spin (HS) centers to one with two high-spin and two low-spin (LS) centres. The spin-crossover sites are located on the same side of the square, and the spin transition and magnetic interactions (see picture) are synergistically coupled.

Original languageEnglish
Pages (from-to)1475-1478
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number8
DOIs
Publication statusPublished - Feb 9 2009

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Self assembly
Iron

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

A spin-crossover cluster of iron(II) exhibiting a mixed-spin structure and synergy between spin transition and magnetic interaction. / Wu, Da Yu; Sato, Osamu; Einaga, Yasuaki; Duan, Chun Ying.

In: Angewandte Chemie - International Edition, Vol. 48, No. 8, 09.02.2009, p. 1475-1478.

Research output: Contribution to journalArticle

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