A stable radical species from facile oxygenation of meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1)

Taro Koide, Gengo Kashiwazaki, Masaaki Suzuki, Ko Furukawa, Min Chul Yoon, Sung Cho, Dongho Kim, Atsuhiro Osuka

Research output: Contribution to journalArticle

68 Citations (Scopus)

Abstract

(Figure Presented) A stable radical: The title compound 1 has been synthesized as the first example of a meso-free variant and characterized as a strongly aromatic macrocycle with a spectacles-like planar conformation. The incorporation of free meso positions is promising for the exploration of novel structural and electronic properties.

Original languageEnglish
Pages (from-to)9661-9665
Number of pages5
JournalAngewandte Chemie - International Edition
Volume47
Issue number50
DOIs
Publication statusPublished - Dec 1 2008
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Fingerprint Dive into the research topics of 'A stable radical species from facile oxygenation of meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1)'. Together they form a unique fingerprint.

  • Cite this