A supramolecular thermocell consisting of ferrocenecarboxylate and β-cyclodextrin that has a negative Seebeck coefficient

Teppei Yamada, Xiaopeng Zou, Yimin Liang, Nobuo Kimizuka

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

A p-type supramolecular thermocell was constructed with a ferrocenecarboxylate/ferroceniumcarboxylate pair. The Seebeck coefficient of the cell was improved from −0.86 to −1.20 mV K−1 by the addition of β-cyclodextrin. Isothermal titration calorimetry and a theoretical investigation demonstrated that the host–guest interaction increased the Seebeck coefficient.

Original languageEnglish
Pages (from-to)771-774
Number of pages4
JournalPolymer Journal
Volume50
Issue number8
DOIs
Publication statusPublished - Aug 1 2018

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Seebeck coefficient
Cyclodextrins
Calorimetry
Titration

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Materials Chemistry

Cite this

A supramolecular thermocell consisting of ferrocenecarboxylate and β-cyclodextrin that has a negative Seebeck coefficient. / Yamada, Teppei; Zou, Xiaopeng; Liang, Yimin; Kimizuka, Nobuo.

In: Polymer Journal, Vol. 50, No. 8, 01.08.2018, p. 771-774.

Research output: Contribution to journalArticle

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