A synthesis of multisubstituted vinylsilanes via ynolates: Stereoselective formation of β-silyl-β-lactones followed by decarboxylation

Mitsuru Shindo, Kenji Matsumoto, Kozo Shishido

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

(Z)-Selective synthesis of multisubstituted vinylsilanes was achieved by stereoselective protonation or alkylation of β-silyl-β-lactone enolates, prepared by cycloadditions of acylsilanes with ynolates, followed by decarboxylation.

Original languageEnglish
Pages (from-to)2477-2479
Number of pages3
JournalChemical Communications
Issue number19
DOIs
Publication statusPublished - May 21 2005

Fingerprint

Cycloaddition
Protonation
Alkylation
Lactones
vinylsilane
Decarboxylation

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

A synthesis of multisubstituted vinylsilanes via ynolates : Stereoselective formation of β-silyl-β-lactones followed by decarboxylation. / Shindo, Mitsuru; Matsumoto, Kenji; Shishido, Kozo.

In: Chemical Communications, No. 19, 21.05.2005, p. 2477-2479.

Research output: Contribution to journalArticle

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