A synthesis of multisubstituted vinylsilanes via ynolates: Stereoselective formation of β-silyl-β-lactones followed by decarboxylation

Mitsuru Shindo; Kenji Matsumoto; Kozo Shishido

doi:10.1039/b418310j

A synthesis of multisubstituted vinylsilanes via ynolates: Stereoselective formation of β-silyl-β-lactones followed by decarboxylation

Mitsuru Shindo, Kenji Matsumoto, Kozo Shishido

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

(Z)-Selective synthesis of multisubstituted vinylsilanes was achieved by stereoselective protonation or alkylation of β-silyl-β-lactone enolates, prepared by cycloadditions of acylsilanes with ynolates, followed by decarboxylation.

Original language	English
Pages (from-to)	2477-2479
Number of pages	3
Journal	Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/b418310j
Publication status	Published - May 21 2005
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b418310j

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abstract = "(Z)-Selective synthesis of multisubstituted vinylsilanes was achieved by stereoselective protonation or alkylation of β-silyl-β-lactone enolates, prepared by cycloadditions of acylsilanes with ynolates, followed by decarboxylation.",

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AU - Matsumoto, Kenji

AU - Shishido, Kozo

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AB - (Z)-Selective synthesis of multisubstituted vinylsilanes was achieved by stereoselective protonation or alkylation of β-silyl-β-lactone enolates, prepared by cycloadditions of acylsilanes with ynolates, followed by decarboxylation.

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A synthesis of multisubstituted vinylsilanes via ynolates: Stereoselective formation of β-silyl-β-lactones followed by decarboxylation

Abstract

All Science Journal Classification (ASJC) codes

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