A Theoretical Treatment of Charge-Transfer Interaction in an Aqueous Solution of Polyelectrolyte

Yoshiya Kawabata; Tomoyuki Itaya; Kazuyoshi Ueda; Yuriko Aoki; Akira Imamura

doi:10.1295/polymj.35.573

A Theoretical Treatment of Charge-Transfer Interaction in an Aqueous Solution of Polyelectrolyte

Yoshiya Kawabata, Tomoyuki Itaya, Kazuyoshi Ueda, Yuriko Aoki, Akira Imamura

Research output: Contribution to journal › Article › peer-review

Abstract

A study was performed on the theoretical treatment of charge-transfer (CT) interaction in an aqueous solution of polyelectrolyte. Molecular orbital theory was adopted to explain theoretically the CT complexation. The results showed that by the approximation of the theory, a distinct linear relation between the energies of the CT absorption band and ionization potentials of the donor molecules was derived although the stoichiometry ratios of CT complexes which formed around the polyion were different.

Original language	English
Pages (from-to)	573-577
Number of pages	5
Journal	Polymer Journal
Volume	35
Issue number	7
DOIs	https://doi.org/10.1295/polymj.35.573
Publication status	Published - Oct 1 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Polymers and Plastics
Materials Chemistry

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abstract = "A study was performed on the theoretical treatment of charge-transfer (CT) interaction in an aqueous solution of polyelectrolyte. Molecular orbital theory was adopted to explain theoretically the CT complexation. The results showed that by the approximation of the theory, a distinct linear relation between the energies of the CT absorption band and ionization potentials of the donor molecules was derived although the stoichiometry ratios of CT complexes which formed around the polyion were different.",

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AU - Itaya, Tomoyuki

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AU - Aoki, Yuriko

AU - Imamura, Akira

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