Abstract
A study was performed on the theoretical treatment of charge-transfer (CT) interaction in an aqueous solution of polyelectrolyte. Molecular orbital theory was adopted to explain theoretically the CT complexation. The results showed that by the approximation of the theory, a distinct linear relation between the energies of the CT absorption band and ionization potentials of the donor molecules was derived although the stoichiometry ratios of CT complexes which formed around the polyion were different.
| Original language | English |
|---|---|
| Pages (from-to) | 573-577 |
| Number of pages | 5 |
| Journal | Polymer Journal |
| Volume | 35 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - Oct 1 2003 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Polymers and Plastics
- Materials Chemistry
Cite this
A Theoretical Treatment of Charge-Transfer Interaction in an Aqueous Solution of Polyelectrolyte. / Kawabata, Yoshiya; Itaya, Tomoyuki; Ueda, Kazuyoshi; Aoki, Yuriko; Imamura, Akira.
In: Polymer Journal, Vol. 35, No. 7, 01.10.2003, p. 573-577.Research output: Contribution to journal › Article
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TY - JOUR
T1 - A Theoretical Treatment of Charge-Transfer Interaction in an Aqueous Solution of Polyelectrolyte
AU - Kawabata, Yoshiya
AU - Itaya, Tomoyuki
AU - Ueda, Kazuyoshi
AU - Aoki, Yuriko
AU - Imamura, Akira
PY - 2003/10/1
Y1 - 2003/10/1
N2 - A study was performed on the theoretical treatment of charge-transfer (CT) interaction in an aqueous solution of polyelectrolyte. Molecular orbital theory was adopted to explain theoretically the CT complexation. The results showed that by the approximation of the theory, a distinct linear relation between the energies of the CT absorption band and ionization potentials of the donor molecules was derived although the stoichiometry ratios of CT complexes which formed around the polyion were different.
AB - A study was performed on the theoretical treatment of charge-transfer (CT) interaction in an aqueous solution of polyelectrolyte. Molecular orbital theory was adopted to explain theoretically the CT complexation. The results showed that by the approximation of the theory, a distinct linear relation between the energies of the CT absorption band and ionization potentials of the donor molecules was derived although the stoichiometry ratios of CT complexes which formed around the polyion were different.
UR - http://www.scopus.com/inward/record.url?scp=0141717979&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0141717979&partnerID=8YFLogxK
U2 - 10.1295/polymj.35.573
DO - 10.1295/polymj.35.573
M3 - Article
AN - SCOPUS:0141717979
VL - 35
SP - 573
EP - 577
JO - Polymer Journal
JF - Polymer Journal
SN - 0032-3896
IS - 7
ER -