TY - JOUR
T1 - A thermally reversible photoinduced magnetic trinuclear complex [Cu 2(bpmen)2][MoIV(CN)8]·8H 2O
AU - Xu, Haitao
AU - Sato, Osamu
AU - Li, Zhihua
AU - Ma, Jianping
N1 - Funding Information:
Financial support from the Japan Society for the Promotion of Science (JSPS) is gratefully acknowledged. This work was supported in part by China Ministry of Education within the project A200-C-1101.
Copyright:
Copyright 2012 Elsevier B.V., All rights reserved.
PY - 2012/1
Y1 - 2012/1
N2 - A trinuclear complex [CuII2(bpmen) 2][MoIV(CN)8]·8H2O was synthesized and structurally characterized, crystallized in the monoclinic system, space group Cc with cell constants a = 11.726(2)Å, b = 17.158(3)Å, c = 23.891(5)Å, β = 97.96(3)° and Z = 4. It exhibited thermally reversible photo-responsive properties on UV light irradiation through a MoIV to CuII charge transfer, which is potential interest for the molecular storage of information as a multifunctional molecule-based material.
AB - A trinuclear complex [CuII2(bpmen) 2][MoIV(CN)8]·8H2O was synthesized and structurally characterized, crystallized in the monoclinic system, space group Cc with cell constants a = 11.726(2)Å, b = 17.158(3)Å, c = 23.891(5)Å, β = 97.96(3)° and Z = 4. It exhibited thermally reversible photo-responsive properties on UV light irradiation through a MoIV to CuII charge transfer, which is potential interest for the molecular storage of information as a multifunctional molecule-based material.
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U2 - 10.1016/j.inoche.2011.11.013
DO - 10.1016/j.inoche.2011.11.013
M3 - Article
AN - SCOPUS:84655160784
VL - 15
SP - 311
EP - 313
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
ER -