A thermally reversible photoinduced magnetic trinuclear complex [Cu 2(bpmen)2][MoIV(CN)8]·8H 2O

Haitao Xu, Osamu Sato, Zhihua Li, Jianping Ma

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18 Citations (Scopus)

Abstract

A trinuclear complex [CuII2(bpmen) 2][MoIV(CN)8]·8H2O was synthesized and structurally characterized, crystallized in the monoclinic system, space group Cc with cell constants a = 11.726(2)Å, b = 17.158(3)Å, c = 23.891(5)Å, β = 97.96(3)° and Z = 4. It exhibited thermally reversible photo-responsive properties on UV light irradiation through a MoIV to CuII charge transfer, which is potential interest for the molecular storage of information as a multifunctional molecule-based material.

Original languageEnglish
Pages (from-to)311-313
Number of pages3
JournalInorganic Chemistry Communications
Volume15
DOIs
Publication statusPublished - Jan 2012

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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