TY - JOUR
T1 - A three-dimensional ferrimagnet with a high magnetic transition temperature (Tc) of 53 K based on a chiral molecule
AU - Inoue, Katsuya
AU - Imai, Hiroyuki
AU - Ghalsasi, Prasanna S.
AU - Kikuchi, Koichi
AU - Ohba, Masaaki
AU - Kawa, Hisashi
AU - Yakhmi, J. V.
PY - 2001/11/19
Y1 - 2001/11/19
N2 - The transparent, double bridged-(R)-spiral three-dimensional polymeric complex K0.4[Cr(CN)6]-[Mn(S)-pn](S)-pnH0.6 ((S)-pn = (S)-1,2-diaminopropane) has been synthesized and characterized (see X-ray structure; Cr: brown, Mn: red, C: gray, N: blue, K: green). Magnetic measurements on the complex show that the MnII and CrIII ions interact ferrimagnetically and magnetic transition occurs at 53 K (Curie temperature).
AB - The transparent, double bridged-(R)-spiral three-dimensional polymeric complex K0.4[Cr(CN)6]-[Mn(S)-pn](S)-pnH0.6 ((S)-pn = (S)-1,2-diaminopropane) has been synthesized and characterized (see X-ray structure; Cr: brown, Mn: red, C: gray, N: blue, K: green). Magnetic measurements on the complex show that the MnII and CrIII ions interact ferrimagnetically and magnetic transition occurs at 53 K (Curie temperature).
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U2 - 10.1002/1521-3773(20011119)40:22<4242::AID-ANIE4242>3.0.CO;2-H
DO - 10.1002/1521-3773(20011119)40:22<4242::AID-ANIE4242>3.0.CO;2-H
M3 - Article
AN - SCOPUS:0035915119
SN - 1433-7851
VL - 40
SP - 4242
EP - 4245
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 22
ER -