A trifluoroacetic acid adduct of a trifluoroacetate-bridged μ4-oxo-tetranuclear zinc cluster, Zn4(OCOCF 3)6O·CF3CO2H: Synthesis under mild conditions and catalytic transesterification and oxazoline formation

Yukiko Hayashi, Takashi Ohshima, Yuka Fujii, Yoshimasa Matsushima, Kazushi Mashima

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27 Citations (Scopus)

Abstract

Synthesis of a trifluoroacetate-bridged tetranuclear zinc cluster and its trifluoroacetic acid (TFA) adduct under mild conditions (∼110°C) was achieved. The catalytic activity and functional group tolerance of the TFA adduct in transesterification and oxazoline formation were almost identical to those of the original zinc cluster.

Original languageEnglish
Pages (from-to)230-233
Number of pages4
JournalCatalysis Science and Technology
Volume1
Issue number2
DOIs
Publication statusPublished - May 1 2011

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Trifluoroacetic acid
Trifluoroacetic Acid
Transesterification
Zinc
Functional groups
Catalyst activity

All Science Journal Classification (ASJC) codes

  • Catalysis

Cite this

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abstract = "Synthesis of a trifluoroacetate-bridged tetranuclear zinc cluster and its trifluoroacetic acid (TFA) adduct under mild conditions (∼110°C) was achieved. The catalytic activity and functional group tolerance of the TFA adduct in transesterification and oxazoline formation were almost identical to those of the original zinc cluster.",
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AU - Fujii, Yuka

AU - Matsushima, Yoshimasa

AU - Mashima, Kazushi

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AB - Synthesis of a trifluoroacetate-bridged tetranuclear zinc cluster and its trifluoroacetic acid (TFA) adduct under mild conditions (∼110°C) was achieved. The catalytic activity and functional group tolerance of the TFA adduct in transesterification and oxazoline formation were almost identical to those of the original zinc cluster.

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