A trifluoroacetic acid adduct of a trifluoroacetate-bridged μ4-oxo-tetranuclear zinc cluster, Zn4(OCOCF 3)6O·CF3CO2H: Synthesis under mild conditions and catalytic transesterification and oxazoline formation

Yukiko Hayashi; Takashi Ohshima; Yuka Fujii; Yoshimasa Matsushima; Kazushi Mashima

doi:10.1039/c0cy00048e

A trifluoroacetic acid adduct of a trifluoroacetate-bridged μ₄-oxo-tetranuclear zinc cluster, Zn₄(OCOCF ₃)₆O·CF₃CO₂H: Synthesis under mild conditions and catalytic transesterification and oxazoline formation

Yukiko Hayashi, Takashi Ohshima, Yuka Fujii, Yoshimasa Matsushima, Kazushi Mashima

Chemo-Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

Synthesis of a trifluoroacetate-bridged tetranuclear zinc cluster and its trifluoroacetic acid (TFA) adduct under mild conditions (∼110°C) was achieved. The catalytic activity and functional group tolerance of the TFA adduct in transesterification and oxazoline formation were almost identical to those of the original zinc cluster.

Original language	English
Pages (from-to)	230-233
Number of pages	4
Journal	Catalysis Science and Technology
Volume	1
Issue number	2
DOIs	https://doi.org/10.1039/c0cy00048e
Publication status	Published - May 2011

All Science Journal Classification (ASJC) codes

Catalysis

Access to Document

10.1039/c0cy00048e

Fingerprint

Dive into the research topics of 'A trifluoroacetic acid adduct of a trifluoroacetate-bridged μ₄-oxo-tetranuclear zinc cluster, Zn₄(OCOCF ₃)₆O·CF₃CO₂H: Synthesis under mild conditions and catalytic transesterification and oxazoline formation'. Together they form a unique fingerprint.

Cite this

A trifluoroacetic acid adduct of a trifluoroacetate-bridged μ₄-oxo-tetranuclear zinc cluster, Zn₄(OCOCF ₃)₆O·CF₃CO₂H: Synthesis under mild conditions and catalytic transesterification and oxazoline formation. / Hayashi, Yukiko; Ohshima, Takashi; Fujii, Yuka et al.
In: Catalysis Science and Technology, Vol. 1, No. 2, 05.2011, p. 230-233.

Research output: Contribution to journal › Article › peer-review

Hayashi, Y, Ohshima, T, Fujii, Y, Matsushima, Y & Mashima, K 2011, 'A trifluoroacetic acid adduct of a trifluoroacetate-bridged μ₄-oxo-tetranuclear zinc cluster, Zn₄(OCOCF ₃)₆O·CF₃CO₂H: Synthesis under mild conditions and catalytic transesterification and oxazoline formation', Catalysis Science and Technology, vol. 1, no. 2, pp. 230-233. https://doi.org/10.1039/c0cy00048e

@article{ae02da609e12480eb0b5fb056bb9ed10,

title = "A trifluoroacetic acid adduct of a trifluoroacetate-bridged μ4-oxo-tetranuclear zinc cluster, Zn4(OCOCF 3)6O·CF3CO2H: Synthesis under mild conditions and catalytic transesterification and oxazoline formation",

abstract = "Synthesis of a trifluoroacetate-bridged tetranuclear zinc cluster and its trifluoroacetic acid (TFA) adduct under mild conditions (∼110°C) was achieved. The catalytic activity and functional group tolerance of the TFA adduct in transesterification and oxazoline formation were almost identical to those of the original zinc cluster.",

author = "Yukiko Hayashi and Takashi Ohshima and Yuka Fujii and Yoshimasa Matsushima and Kazushi Mashima",

year = "2011",

month = may,

doi = "10.1039/c0cy00048e",

language = "English",

volume = "1",

pages = "230--233",

journal = "Catalysis Science and Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - A trifluoroacetic acid adduct of a trifluoroacetate-bridged μ4-oxo-tetranuclear zinc cluster, Zn4(OCOCF 3)6O·CF3CO2H

T2 - Synthesis under mild conditions and catalytic transesterification and oxazoline formation

AU - Hayashi, Yukiko

AU - Ohshima, Takashi

AU - Fujii, Yuka

AU - Matsushima, Yoshimasa

AU - Mashima, Kazushi

PY - 2011/5

Y1 - 2011/5

N2 - Synthesis of a trifluoroacetate-bridged tetranuclear zinc cluster and its trifluoroacetic acid (TFA) adduct under mild conditions (∼110°C) was achieved. The catalytic activity and functional group tolerance of the TFA adduct in transesterification and oxazoline formation were almost identical to those of the original zinc cluster.

AB - Synthesis of a trifluoroacetate-bridged tetranuclear zinc cluster and its trifluoroacetic acid (TFA) adduct under mild conditions (∼110°C) was achieved. The catalytic activity and functional group tolerance of the TFA adduct in transesterification and oxazoline formation were almost identical to those of the original zinc cluster.

UR - http://www.scopus.com/inward/record.url?scp=79955405777&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=79955405777&partnerID=8YFLogxK

U2 - 10.1039/c0cy00048e

DO - 10.1039/c0cy00048e

M3 - Article

AN - SCOPUS:79955405777

SN - 2044-4753

VL - 1

SP - 230

EP - 233

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 2

ER -