A water-soluble iridium(III) porphyrin

Hironobu Kanemitsu, Ryosuke Harada, Seiji Ogo

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Abstract

This work reports the synthesis and characterization of the first water-soluble iridium porphyrin, iridium(III) diaqua porphyrin [Ir III(TSPP)(OH2)2]3- (1, TSPP = tetra-p-sulfonatophenyl porphyrin). The structure of 1 was unequivocally determined by single crystal X-ray analysis. Benzo-18-crown-6-ether is essential for producing single crystals suitable for X-ray analysis.

Original languageEnglish
Pages (from-to)3083-3085
Number of pages3
JournalChemical Communications
Volume46
Issue number18
DOIs
Publication statusPublished - May 10 2010

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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