A Water-soluble Ni Dihydrido Complex That Reduces O2 to H2O in Water

Keisuke Takashita, Takahiro Matsumoto, Takeshi Yatabe, Hidetaka Nakai, Masatatsu Suzuki, Seiji Ogo

Research output: Contribution to journalArticle

Abstract

We report the first example of reduction of O2 to H2O by a Ni(II) dihydrido species. Isotope-labeling experiments reveal a four-electron reduction of O2 by the dihydrido species. The water-soluble Ni(II) dihydrido species was characterized by X-ray analysis, electrospray ionization mass spectrometry, and IR, 1HNMR, ESR, and UV-vis spectroscopies.

Original languageEnglish
Pages (from-to)72-74
Number of pages3
JournalChemistry Letters
Volume45
Issue number1
DOIs
Publication statusPublished - Jan 1 2016

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Electrospray ionization
Water
X ray analysis
Ultraviolet spectroscopy
Isotopes
Labeling
Mass spectrometry
Paramagnetic resonance
Electrons
Experiments

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

A Water-soluble Ni Dihydrido Complex That Reduces O2 to H2O in Water. / Takashita, Keisuke; Matsumoto, Takahiro; Yatabe, Takeshi; Nakai, Hidetaka; Suzuki, Masatatsu; Ogo, Seiji.

In: Chemistry Letters, Vol. 45, No. 1, 01.01.2016, p. 72-74.

Research output: Contribution to journalArticle

Takashita, Keisuke ; Matsumoto, Takahiro ; Yatabe, Takeshi ; Nakai, Hidetaka ; Suzuki, Masatatsu ; Ogo, Seiji. / A Water-soluble Ni Dihydrido Complex That Reduces O2 to H2O in Water. In: Chemistry Letters. 2016 ; Vol. 45, No. 1. pp. 72-74.
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