A Water-soluble Ni Dihydrido Complex That Reduces O2 to H2O in Water

Keisuke Takashita, Takahiro Matsumoto, Takeshi Yatabe, Hidetaka Nakai, Masatatsu Suzuki, Seiji Ogo

Research output: Contribution to journalArticle

Abstract

We report the first example of reduction of O2 to H2O by a Ni(II) dihydrido species. Isotope-labeling experiments reveal a four-electron reduction of O2 by the dihydrido species. The water-soluble Ni(II) dihydrido species was characterized by X-ray analysis, electrospray ionization mass spectrometry, and IR, 1HNMR, ESR, and UV-vis spectroscopies.

Original languageEnglish
Pages (from-to)72-74
Number of pages3
JournalChemistry Letters
Volume45
Issue number1
DOIs
Publication statusPublished - Jan 1 2016

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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