TY - JOUR
T1 - Acridinium ester chemiluminescence
T2 - Methyl substitution on the acridine moiety
AU - Nakazono, Manabu
AU - Nanbu, Shinkoh
AU - Akita, Takeyuki
AU - Hamase, Kenji
N1 - Funding Information:
This work was financially supported by the Kakihara Science and Technology Research Foundation(Grant No. 2-9-1). This work was the result of the use of research equipment shared in a MEXT Project for the promotion of the public utilization of advanced research infrastructure (Program supporting the introduction of the new sharing system, Grant No. JPMXS0422300120). We are grateful to Prof. Takashi Ito(Graduate School of Medical Sciences)and Prof. Satoshi Okada(Graduate School of Medical Sciences) at Kyushu University for detailed guidance for regarding the measurement of chemiluminescence spectra.
Funding Information:
This work was financially supported by the Kakihara Science and Technology Research Foundation（Grant No. 2-9-1）. This work was the result of the use of research equipment shared in a MEXT Project for the promotion of the public utilization of advanced research infrastructure （Program supporting the introduction of the new sharing system, Grant No. JPMXS0422300120）. We are grateful to Prof. Takashi Ito（Graduate School of Medical Sciences）and Prof. Satoshi Okad（a Graduate School of Medical Sciences） at Kyushu University for detailed guidance for regarding the measurement of chemiluminescence spectra.
Publisher Copyright:
© 2021 by Japan Oil Chemists’ Society.
PY - 2021
Y1 - 2021
N2 - Methyl groups were introduced on the acridine moiety in chemiluminescent acridinium esters that have electron-withdrawing groups (trifluoromethyl, cyano, nitro, ethoxycarbonyl) at the 4-position on the phenyl ester. The introduction of methyl groups at the 2-, 2, 7-, and 2, 3, 6, 7-positions on the acridine moiety shifted the optimal pH that gave relatively strong chemiluminescence intensity from neutral conditions to alkaline conditions. 4-(Ethoxycarbonyl)phenyl 2, 3, 6, 7, 10-pentamethyl-10λ4-acridine-9- carboxylate, trifluoromethanesulfonate salt showed long-lasting chemiluminescence under alkaline conditions. Acridinium esters to determine hydrogen peroxide concentration at pH 7-10 were newly developed.
AB - Methyl groups were introduced on the acridine moiety in chemiluminescent acridinium esters that have electron-withdrawing groups (trifluoromethyl, cyano, nitro, ethoxycarbonyl) at the 4-position on the phenyl ester. The introduction of methyl groups at the 2-, 2, 7-, and 2, 3, 6, 7-positions on the acridine moiety shifted the optimal pH that gave relatively strong chemiluminescence intensity from neutral conditions to alkaline conditions. 4-(Ethoxycarbonyl)phenyl 2, 3, 6, 7, 10-pentamethyl-10λ4-acridine-9- carboxylate, trifluoromethanesulfonate salt showed long-lasting chemiluminescence under alkaline conditions. Acridinium esters to determine hydrogen peroxide concentration at pH 7-10 were newly developed.
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U2 - 10.5650/jos.ess21186
DO - 10.5650/jos.ess21186
M3 - Article
C2 - 34732638
AN - SCOPUS:85120666897
VL - 70
SP - 1677
EP - 1684
JO - Journal of Oleo Science
JF - Journal of Oleo Science
SN - 1345-8957
IS - 11
ER -