Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation

Shunichi Fukuzumi; Hironori Kitaguchi; Tomoyoshi Suenobu; Seiji Ogo

doi:10.1039/b205517a

Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation

Shunichi Fukuzumi, Hironori Kitaguchi, Tomoyoshi Suenobu, Seiji Ogo

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Electron transfer reduction of p-benzoquinones by cobalt tetraphenylporphyrin is enhanced significantly by the presence of o-bis(phenylcarbamoylmethyl)benzene (o-L) due to the regioselective hydrogen bond formation between the corresponding semiquinone radical anions and o-L, whereas m- and p-isomers (m-L and p-L) have no effect on the electron transfer equilibrium or the rate.

Original language	English
Pages (from-to)	1984-1985
Number of pages	2
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/b205517a
Publication status	Published - Jan 1 2002
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Electron transfer reduction of p-benzoquinones by cobalt tetraphenylporphyrin is enhanced significantly by the presence of o-bis(phenylcarbamoylmethyl)benzene (o-L) due to the regioselective hydrogen bond formation between the corresponding semiquinone radical anions and o-L, whereas m- and p-isomers (m-L and p-L) have no effect on the electron transfer equilibrium or the rate.",

author = "Shunichi Fukuzumi and Hironori Kitaguchi and Tomoyoshi Suenobu and Seiji Ogo",

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T1 - Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation

AU - Fukuzumi, Shunichi

AU - Kitaguchi, Hironori

AU - Suenobu, Tomoyoshi

AU - Ogo, Seiji

PY - 2002/1/1

Y1 - 2002/1/1

N2 - Electron transfer reduction of p-benzoquinones by cobalt tetraphenylporphyrin is enhanced significantly by the presence of o-bis(phenylcarbamoylmethyl)benzene (o-L) due to the regioselective hydrogen bond formation between the corresponding semiquinone radical anions and o-L, whereas m- and p-isomers (m-L and p-L) have no effect on the electron transfer equilibrium or the rate.

AB - Electron transfer reduction of p-benzoquinones by cobalt tetraphenylporphyrin is enhanced significantly by the presence of o-bis(phenylcarbamoylmethyl)benzene (o-L) due to the regioselective hydrogen bond formation between the corresponding semiquinone radical anions and o-L, whereas m- and p-isomers (m-L and p-L) have no effect on the electron transfer equilibrium or the rate.

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U2 - 10.1039/b205517a

DO - 10.1039/b205517a

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SP - 1984

EP - 1985

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation

Abstract

All Science Journal Classification (ASJC) codes

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