Additive effect of N-heteroaromatics on transesterification catalyzed by tetranuclear zinc cluster

Yusuke Maegawa; Takashi Ohshima; Yukiko Hayashi; Kazushi Agura; Takanori Iwasaki; Kazushi Mashima

doi:10.1021/cs200224b

Additive effect of N-heteroaromatics on transesterification catalyzed by tetranuclear zinc cluster

Yusuke Maegawa, Takashi Ohshima, Yukiko Hayashi, Kazushi Agura, Takanori Iwasaki, Kazushi Mashima

Chemo-Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

A catalytic amount of 4-dimethylaminopyridine showed drastic additive effects on transesterification catalyzed by the μ₄-oxo- tetranuclear zinc cluster Zn₄(OCOCF₃)₆O, enhancing the catalytic activity by more than 15-fold. The new catalyst system facilitates transesterification of less reactive sterically demanding esters and alcohols.

Original language	English
Pages (from-to)	1178-1182
Number of pages	5
Journal	ACS Catalysis
Volume	1
Issue number	10
DOIs	https://doi.org/10.1021/cs200224b
Publication status	Published - Oct 7 2011

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1021/cs200224b

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abstract = "A catalytic amount of 4-dimethylaminopyridine showed drastic additive effects on transesterification catalyzed by the μ4-oxo- tetranuclear zinc cluster Zn4(OCOCF3)6O, enhancing the catalytic activity by more than 15-fold. The new catalyst system facilitates transesterification of less reactive sterically demanding esters and alcohols.",

author = "Yusuke Maegawa and Takashi Ohshima and Yukiko Hayashi and Kazushi Agura and Takanori Iwasaki and Kazushi Mashima",

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AU - Maegawa, Yusuke

AU - Ohshima, Takashi

AU - Hayashi, Yukiko

AU - Agura, Kazushi

AU - Iwasaki, Takanori

AU - Mashima, Kazushi

PY - 2011/10/7

Y1 - 2011/10/7

N2 - A catalytic amount of 4-dimethylaminopyridine showed drastic additive effects on transesterification catalyzed by the μ4-oxo- tetranuclear zinc cluster Zn4(OCOCF3)6O, enhancing the catalytic activity by more than 15-fold. The new catalyst system facilitates transesterification of less reactive sterically demanding esters and alcohols.

AB - A catalytic amount of 4-dimethylaminopyridine showed drastic additive effects on transesterification catalyzed by the μ4-oxo- tetranuclear zinc cluster Zn4(OCOCF3)6O, enhancing the catalytic activity by more than 15-fold. The new catalyst system facilitates transesterification of less reactive sterically demanding esters and alcohols.

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ER -

Additive effect of N-heteroaromatics on transesterification catalyzed by tetranuclear zinc cluster

Abstract

All Science Journal Classification (ASJC) codes

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