Additive effect of N-heteroaromatics on transesterification catalyzed by tetranuclear zinc cluster

Yusuke Maegawa; Takashi Ohshima; Yukiko Hayashi; Kazushi Agura; Takanori Iwasaki; Kazushi Mashima

doi:10.1021/cs200224b

Additive effect of N-heteroaromatics on transesterification catalyzed by tetranuclear zinc cluster

Yusuke Maegawa, Takashi Ohshima, Yukiko Hayashi, Kazushi Agura, Takanori Iwasaki, Kazushi Mashima

Chemo-Pharmaceutical Sciences

Research output: Contribution to journal › Article

44 Citations (Scopus)

Abstract

A catalytic amount of 4-dimethylaminopyridine showed drastic additive effects on transesterification catalyzed by the μ₄-oxo- tetranuclear zinc cluster Zn₄(OCOCF₃)₆O, enhancing the catalytic activity by more than 15-fold. The new catalyst system facilitates transesterification of less reactive sterically demanding esters and alcohols.

Original language	English
Pages (from-to)	1178-1182
Number of pages	5
Journal	ACS Catalysis
Volume	1
Issue number	10
DOIs	https://doi.org/10.1021/cs200224b
Publication status	Published - Oct 7 2011

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All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

Cite this

Maegawa, Y., Ohshima, T., Hayashi, Y., Agura, K., Iwasaki, T., & Mashima, K. (2011). Additive effect of N-heteroaromatics on transesterification catalyzed by tetranuclear zinc cluster. ACS Catalysis, 1(10), 1178-1182. https://doi.org/10.1021/cs200224b

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Access to Document

10.1021/cs200224b