Aerobic C-H Oxidation of Arenes Using a Recyclable, Heterogeneous Rhodium Catalyst

Kenji Matsumoto, Shohei Tachikawa, Noriko Hashimoto, Rina Nakano, Masahiro Yoshida, Mitsuru Shindo

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

A novel, practical protocol for the aerobic direct C-H acetoxylation of arenes, employing a recyclable heterogeneous rhodium catalyst, is reported herein. The trifluoroacetoxylation of 2-amido-substituted anthracenes proceeded at the 9-position with exclusive regioselectivity. The oxidation of variously substituted anthracenes and other polycyclic aromatics with molecular oxygen as a terminal oxidant proceeded under mild conditions, providing products in good to excellent yields.

Original languageEnglish
Pages (from-to)4305-4316
Number of pages12
JournalJournal of Organic Chemistry
Volume82
Issue number8
DOIs
Publication statusPublished - Apr 21 2017

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Anthracenes
Rhodium
Regioselectivity
Oxidation
Catalysts
Molecular oxygen
Oxidants

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

Aerobic C-H Oxidation of Arenes Using a Recyclable, Heterogeneous Rhodium Catalyst. / Matsumoto, Kenji; Tachikawa, Shohei; Hashimoto, Noriko; Nakano, Rina; Yoshida, Masahiro; Shindo, Mitsuru.

In: Journal of Organic Chemistry, Vol. 82, No. 8, 21.04.2017, p. 4305-4316.

Research output: Contribution to journalArticle

Matsumoto, Kenji ; Tachikawa, Shohei ; Hashimoto, Noriko ; Nakano, Rina ; Yoshida, Masahiro ; Shindo, Mitsuru. / Aerobic C-H Oxidation of Arenes Using a Recyclable, Heterogeneous Rhodium Catalyst. In: Journal of Organic Chemistry. 2017 ; Vol. 82, No. 8. pp. 4305-4316.
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