Aerobic catechol oxidation catalyzed by a bis(μ-oxo)dimanganese(III,III) complex via a manganese(II)-semiquinonate complex

Yutaka Hitomi, Akira Ando, Hajime Matsui, Tomoyuki Ito, Tsunehiro Tanaka, Seiji Ogo, Takuzo Funabiki

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58 Citations (Scopus)

Abstract

A 3,5-di-terf-butyl-1,2-semiquinonato (DTBSQ) adduct of Mn(II) was prepared by a reaction between MnII(TPA)Cl2 (TPA = tris(pyridin-2-ylmethyl)amine) and DTBSQ anion and was isolated as a tetraphenylborate salt. The X-ray crystal structure revealed that the complex is formulated as a manganese(II)-semiquinonate complex [MnII(TPA) (DTBSQ)]+ (1). The electronic spectra in solution also indicated the semiquinonate coordination to Mn. The exposure of 1 in acetonitrile to dioxygen afforded 3,5-di-tert-butyl-1,2-benzoquione and a bis(μ-oxo)dimanganese(III, III) complex [MnIII2(μ-oxo)2(TPA) 2]2+ (2). The reaction of 2 with 3,5-di-terf-butylcatechol (DTBCH2) quantitatively afforded two equivalents of 1 under anaerobic conditions. The highly efficient catalytic oxidation of DTBCH 2 with dioxygen was achieved by combining the above two reactions, that is, by constructing a catalytic cycle involving both manganese complexes 1 and 2. It was revealed that dioxygen is reduced to water but not to hydrogen peroxide in the catalytic cycle.

Original languageEnglish
Pages (from-to)3473-3478
Number of pages6
JournalInorganic Chemistry
Volume44
Issue number10
DOIs
Publication statusPublished - May 16 2005
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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