TY - JOUR
T1 - Aerobic Electrochemical Transformations of DDT to Oxygen-Incorporated Products Catalyzed by a B12 Derivative
AU - Moniruzzaman, Mohammad
AU - Yano, Yoshio
AU - Ono, Toshikazu
AU - Hisaeda, Yoshio
AU - Shimakoshi, Hisashi
N1 - Funding Information:
This study was partially supported by a Grant-in-Aid for Scientific Research (B) (JP19H02735) from the Japan Society for the Promotion of Science (JSPS). Part of the study was performed under the Cooperative Research Program of “Network Joint Research Center for Materials and Devices: Dynamic Alliance for Open Innovation Bridging Human, Environment and Materials” (20214031) and a Grant from the Takahashi Industrial and Economic Research Foundation (11-003-359).
Publisher Copyright:
© 2021 The Chemical Society of Japan
PY - 2021
Y1 - 2021
N2 - Electrochemical transformations of DDT into oxygen-incorporated products, amides and esters, catalyzed by a B12 derivative, heptamethyl cobyrinate perchlorate, have been developed under aerobic conditions. The dechlorinative oxygenation of DDT forms the acyl chloride as an intermediate for the synthesis of the amide and ester in the reaction with the amine and alcohol, respectively. This electrochemical method demonstrated with 20 oxygen-incorporated dechlorinated products up to 88% yields with 15 new compounds and was also successfully applied to the conversion of methoxychlor to an amide and ester.
AB - Electrochemical transformations of DDT into oxygen-incorporated products, amides and esters, catalyzed by a B12 derivative, heptamethyl cobyrinate perchlorate, have been developed under aerobic conditions. The dechlorinative oxygenation of DDT forms the acyl chloride as an intermediate for the synthesis of the amide and ester in the reaction with the amine and alcohol, respectively. This electrochemical method demonstrated with 20 oxygen-incorporated dechlorinated products up to 88% yields with 15 new compounds and was also successfully applied to the conversion of methoxychlor to an amide and ester.
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U2 - 10.1246/bcsj.20210316
DO - 10.1246/bcsj.20210316
M3 - Article
AN - SCOPUS:85122629998
SN - 0009-2673
VL - 94
SP - 2784
EP - 2791
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 11
ER -