Aerobic Oxidative Intramolecular Aromatic Coupling via Heterogeneous Metal Catalysts

Shigenobu Fujimoto, Kenji Matsumoto, Mitsuru Shindo

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

An aerobic, heterogeneously catalyzed oxidative intramolecular coupling reaction of aromatic compounds is reported here. Using commercially available, recyclable heterogeneous metal catalysts, the coupling reactions of o-terphenyls and 1,ω-biarylalkanes proceeded quickly under mild conditions, i.e., at room temperature under oxygen as a co-oxidant almost all within 1 h, to provide the corresponding coupled products like triphenylenes and phenanthrenes in good to excellent yields. This reaction is an easily handled, practical, and atom-economical coupling method, which is of great importance in modern organic syntheses. (Figure presented.).

Original languageEnglish
Pages (from-to)3057-3061
Number of pages5
JournalAdvanced Synthesis and Catalysis
Volume358
Issue number19
DOIs
Publication statusPublished - Jan 1 2016

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

Fingerprint Dive into the research topics of 'Aerobic Oxidative Intramolecular Aromatic Coupling via Heterogeneous Metal Catalysts'. Together they form a unique fingerprint.

  • Cite this