Aggregation-induced photon upconversion through control of the triplet energy landscapes of the solution and solid states

Pengfei Duan, Nobuhiro Yanai, Yuki Kurashige, Nobuo Kimizuka

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    59 Citations (Scopus)

    Abstract

    Aggregation-induced photon upconversion (iPUC) based on control of the triplet energy landscape is demonstrated for the first time. When a triplet state of a cyano-substituted 1,4-distyrylbenzene derivative is sensitized in solution, no upconverted emission based on triplet-triplet annihilation (TTA) was observed. In stark contrast, crystalline solids obtained by drying the solution revealed clear upconverted emission. Theoretical studies unveiled an underlying switching mechanism: the excited triplets in solution immediately decay back to the ground state through conformational twisting around a C-C bond and photoisomerization, whereas this deactivation path is effectively inhibited in the solid state. The finding of iPUC phenomena highlights the importance of controlling excited energy landscapes in condensed molecular systems. Affairs of state: Whereas a cyano-substituted 1,4-distyrylbenzene derivative shows no upconverted (UC) emission in solution, a clear upconverted emission is observed for solution-cast crystals (see picture). The difference is attributed to immediate decay of excited triplets through conformational twisting and isomerization being possible in solution but not in the solid state.

    Original languageEnglish
    Pages (from-to)7544-7549
    Number of pages6
    JournalAngewandte Chemie - International Edition
    Volume54
    Issue number26
    DOIs
    Publication statusPublished - Jun 1 2015

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Chemistry(all)

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