Aggregation States of Poly(4-methylpentene-1) at a Solid Interface

Kentaro Yamamoto, Daisuke Kawaguchi, Kazuki Sasahara, Manabu Inutsuka, Satoru Yamamoto, Kiminori Uchida, Kazuki Mita, Hiroki Ogawa, Mikihito Takenaka, Keiji Tanaka

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

A thin film of poly(4-methylpentene-1) (P4MP1) was prepared on a quartz substrate, which was a model system of an interface in filler-reinforced semicrystalline polymer composites. Grazing-incidence wide-angle X-ray diffraction measurements revealed that P4MP1 in the thin film after isothermal crystallization formed a Form I crystal polymorph composed of a tetragonal unit cell with a 72 helix, in which the chain axis was oriented along the direction parallel to the quartz interface. Combining sum-frequency generation vibrational spectroscopy with molecular dynamics simulation enabled us to gain access to the local conformation of P4MP1 chains at the quartz interface and the changes that occurred with isothermal crystallization. Finally, the way in which the initial chain orientation at the substrate interface impacted the crystalline structure in the thin film was discussed.

Original languageEnglish
Pages (from-to)247-255
Number of pages9
JournalPolymer Journal
Volume51
Issue number2
DOIs
Publication statusPublished - Feb 1 2019

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Materials Chemistry

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