Abstract
A new method to synthesize polymer electrolyte membranes based on charge-transfer (CT) complexes for high temperature fuel cells is investigated. Aliphatic sulfonated polyimide (SPI) CT complex hybrid films are prepared. Aliphatic units are introduced into the SPI main chain to increase the elasticity compared with aromatic SPI films. Electron-donating compounds are included to form a CT complex, resulting in improved control over mechanical strength, water uptake, and thermal stability. The resulting thermal properties of the SPI CT films are sufficient to operate at elevated temperature (up to 120 °C), and the proton conductivity is comparable to that of Nafion 115. These films are thus promising alternative membranes for high temperature polymer electrolyte fuel cell applications.
| Original language | English |
|---|---|
| Article number | 46087 |
| Journal | Journal of Applied Polymer Science |
| Volume | 135 |
| Issue number | 14 |
| DOIs | |
| Publication status | Published - Apr 10 2018 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Surfaces, Coatings and Films
- Polymers and Plastics
- Materials Chemistry
Cite this
Aliphatic SPI charge-transfer complex hybrid films for high temperature polymer electrolyte membrane fuel cells. / Christiani, Liana; Sasaki, Kazunari; Nishihara, Masamichi.
In: Journal of Applied Polymer Science, Vol. 135, No. 14, 46087, 10.04.2018.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Aliphatic SPI charge-transfer complex hybrid films for high temperature polymer electrolyte membrane fuel cells
AU - Christiani, Liana
AU - Sasaki, Kazunari
AU - Nishihara, Masamichi
PY - 2018/4/10
Y1 - 2018/4/10
N2 - A new method to synthesize polymer electrolyte membranes based on charge-transfer (CT) complexes for high temperature fuel cells is investigated. Aliphatic sulfonated polyimide (SPI) CT complex hybrid films are prepared. Aliphatic units are introduced into the SPI main chain to increase the elasticity compared with aromatic SPI films. Electron-donating compounds are included to form a CT complex, resulting in improved control over mechanical strength, water uptake, and thermal stability. The resulting thermal properties of the SPI CT films are sufficient to operate at elevated temperature (up to 120 °C), and the proton conductivity is comparable to that of Nafion 115. These films are thus promising alternative membranes for high temperature polymer electrolyte fuel cell applications.
AB - A new method to synthesize polymer electrolyte membranes based on charge-transfer (CT) complexes for high temperature fuel cells is investigated. Aliphatic sulfonated polyimide (SPI) CT complex hybrid films are prepared. Aliphatic units are introduced into the SPI main chain to increase the elasticity compared with aromatic SPI films. Electron-donating compounds are included to form a CT complex, resulting in improved control over mechanical strength, water uptake, and thermal stability. The resulting thermal properties of the SPI CT films are sufficient to operate at elevated temperature (up to 120 °C), and the proton conductivity is comparable to that of Nafion 115. These films are thus promising alternative membranes for high temperature polymer electrolyte fuel cell applications.
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UR - http://www.scopus.com/inward/citedby.url?scp=85039171986&partnerID=8YFLogxK
U2 - 10.1002/app.46087
DO - 10.1002/app.46087
M3 - Article
AN - SCOPUS:85039171986
VL - 135
JO - Journal of Applied Polymer Science
JF - Journal of Applied Polymer Science
SN - 0021-8995
IS - 14
M1 - 46087
ER -