Alkylcobyrinate from sucralose and mechanistic aspects of its CoC bond cleavage

Hitesh V. Motwani, Hisashi Shimakoshi, Bernard T. Golding, Margareta Törnqvist, Yoshio Hisaeda

    Research output: Contribution to journalArticlepeer-review

    2 Citations (Scopus)

    Abstract

    Reaction of heptamethyl cob(I)yrinate with 1′,6′-dichloro- 1′,6′-dideoxy-β-d-fructofuranosyl-4-chloro-4-deoxy-α-d- galactopyranoside (sucralose) gave an alkylcobyrinate, heptamethyl-6′- [α-d-galactopyranoside- 1′-chloro-1′,6′-dideoxy-β- d-fructofuranosyl-4-chloro-4-deoxy]cobyrinate perchlorate, [(Suc)Cob(III)7C 1ester]ClO4. Cleavage behavior of CoC bond of the alkylcobyrinate was investigated under various conditions (hν, H+ and reduction) using UV-vis spectroscopy combined with the EPR spin-trapping technique, and by cyclic voltammetry.

    Original languageEnglish
    Pages (from-to)2667-2670
    Number of pages4
    JournalTetrahedron Letters
    Volume55
    Issue number16
    DOIs
    Publication statusPublished - Apr 16 2014

    All Science Journal Classification (ASJC) codes

    • Biochemistry
    • Drug Discovery
    • Organic Chemistry

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