TY - JOUR
T1 - Allyldialkyl complexes of ruthenium(IV)
T2 - Preparation and reductive CC bond formation followed by CH bond activation
AU - Nagashima, Hideo
AU - Ara, Ken Ichi
AU - Yamaguchi, Keitaro
AU - Itoh, Kenji
N1 - Funding Information:
Acknowledgment. One of the authors (K.I.) is grateful to the Ministry of Education, Science, and Culture for a Grant-in-Aid for Special Project Research, and to Mitsubishi Chemical Industry Co. Ltd., for financial support.
PY - 1987/1/13
Y1 - 1987/1/13
N2 - New η3-allyldimethyl complexes Ru(η5-C5R5)(η3-C3H5)(CH3)2, where R = H or CH3, are prepared from Ru(η5-C5R5)(η3-C3H5)Br2 by alkylation with trimethyl-aluminium. The RuIV dimethyl complex is thermally converted to the RuII 1-methylallyl compound, Ru(η5-C5R5)(η3-CH2CHCHCH3)L, where L = CO or t-C4H9NC, with evolution of methane. Kinetic and deuteration studies on the reductive process are also discussed.
AB - New η3-allyldimethyl complexes Ru(η5-C5R5)(η3-C3H5)(CH3)2, where R = H or CH3, are prepared from Ru(η5-C5R5)(η3-C3H5)Br2 by alkylation with trimethyl-aluminium. The RuIV dimethyl complex is thermally converted to the RuII 1-methylallyl compound, Ru(η5-C5R5)(η3-CH2CHCHCH3)L, where L = CO or t-C4H9NC, with evolution of methane. Kinetic and deuteration studies on the reductive process are also discussed.
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U2 - 10.1016/0022-328X(87)80358-3
DO - 10.1016/0022-328X(87)80358-3
M3 - Article
AN - SCOPUS:25344461062
SN - 0022-328X
VL - 319
SP - C11-C15
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -