Amine-Functionalized Diamond Electrode for Boosting CO2Reduction to CO

Tatsuhiko Mikami, Takashi Yamamoto, Mai Tomisaki, Yasuaki Einaga

Research output: Contribution to journalArticlepeer-review

Abstract

Carbon capture, utilization, and storage (CCUS) have been attracting much attention as an initiative to achieve carbon neutrality. In the capture and storage strategy, amines are widely used for highly efficient separation and capturing of CO2since amines react with CO2to form carbamates. In the utilization strategy, CO2electroreduction is a promising method to convert CO2into value-added compounds because reaction conditions are relatively mild and easily controlled. In this work, toward combining CO2capture and storage technologies and CO2electroreduction, we focused on amine modification of the electrode surface, in which boron-doped diamond (BDD) was chosen as a sustainable electrode material. CO2electroreduction using the amine-modified BDD was performed, and an applied potential dependence of the product selectivity was examined. In situ attenuated total reflectance-infrared measurements showed that the peak intensity of the stretching vibration of the carbonyl group at around 1640 cm-1decreased as applied potentials became more negative. The effect of amine modification of the BDD surface lies in the formation of a C-N bond during CO2electroreduction, resulting in the enhancement of the selectivity of CO production up to 8 times compared to the unmodified BDD.

Original languageEnglish
Pages (from-to)14685-14692
Number of pages8
JournalACS Sustainable Chemistry and Engineering
Volume10
Issue number45
DOIs
Publication statusPublished - Nov 14 2022
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Renewable Energy, Sustainability and the Environment

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