@article{91e7036749ed417aaff007cc232c76af,
title = "Amine/hydrido bifunctional nanoporous silica with small metal nanoparticles made onsite: Efficient dehydrogenation catalyst",
abstract = "Multifunctional catalysts are of great interest in catalysis because their multiple types of catalytic or functional groups can cooperatively promote catalytic transformations better than their constituents do individually. Herein we report a new synthetic route involving the surface functionalization of nanoporous silica with a rationally designed and synthesized dihydrosilane (3-aminopropylmethylsilane) that leads to the introduction of catalytically active grafted organoamine as well as single metal atoms and ultrasmall Pd or Ag-doped Pd nanoparticles via on-site reduction of metal ions. The resulting nanomaterials serve as highly effective bifunctional dehydrogenative catalysts for generation of H2 from formic acid.",
author = "Yang Zhu and Takahiro Nakanishi and Kazuyoshi Kanamori and Kazuki Nakanishi and Shun Ichii and Kohji Iwaida and Yu Masui and Toshiyuki Kamei and Toyoshi Shimada and Akihito Kumamoto and Ikuhara, {Yumi H.} and Mina Jeon and George Hasegawa and Tewodros Asefa and Masamoto Tafu and Yoon, {Chang Won}",
note = "Funding Information: The work was financially supported by the Advanced Low Carbon Technology Research and Development Program from the Japan Science and Technology Agency and Japan Society for the Promotion of Science (JSPS), Grant 15J00156. A part of this work was supported by {"}Nanotechnology Platform{"} (Project 12024046) of the Ministry of Education, Culture, Sports, Science and Technology, Japan and by JSPS KAKENHI, Grant JP26288106. Prof. Hiroki Kurata and Mr. Tsutomu Kiyomura are greatly acknowledged for their help with TEM analysis. T.A. gratefully acknowledges Prof. K. Nakanishi and his research group for hosting him during his sabbatical, which led to the ideas as well as the fruits behind this international collaborative research work. Part of the research was also supported by the Technology Development Program to Solve Climate Changes of the National Research Foundation (NRF) funded by the Ministry of Science, ICT & Future Planning in Republic of Korea (2015M1A2A2074688). Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",
year = "2017",
month = jan,
day = "11",
doi = "10.1021/acsami.6b12972",
language = "English",
volume = "9",
pages = "36--41",
journal = "ACS applied materials & interfaces",
issn = "1944-8244",
publisher = "American Chemical Society",
number = "1",
}