An abrupt spin transition based on short S⋯S contacts in a novel Fe(II) complex whose ligand contains a 1,3-dithiole ring

Kazuyuki Takahashi, Tomoko Kawakami, Zhong Ze Gu, Yasuaki Einaga, Akira Fujishima, Osamu Sato

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The first preparation of an Fe(II) spin-crossover complex including a 1,3-dithiole ligand is reported. Crystal analyses of both the low- and the high-temperature phases reveal that short S⋯S contacts play a key role in an abrupt spin transition.

Original languageEnglish
Pages (from-to)2374-2375
Number of pages2
JournalChemical Communications
Volume3
Issue number18
DOIs
Publication statusPublished - Jan 1 2003
Externally publishedYes

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Ligands
Crystals
Temperature

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

An abrupt spin transition based on short S⋯S contacts in a novel Fe(II) complex whose ligand contains a 1,3-dithiole ring. / Takahashi, Kazuyuki; Kawakami, Tomoko; Gu, Zhong Ze; Einaga, Yasuaki; Fujishima, Akira; Sato, Osamu.

In: Chemical Communications, Vol. 3, No. 18, 01.01.2003, p. 2374-2375.

Research output: Contribution to journalArticle

Takahashi, Kazuyuki ; Kawakami, Tomoko ; Gu, Zhong Ze ; Einaga, Yasuaki ; Fujishima, Akira ; Sato, Osamu. / An abrupt spin transition based on short S⋯S contacts in a novel Fe(II) complex whose ligand contains a 1,3-dithiole ring. In: Chemical Communications. 2003 ; Vol. 3, No. 18. pp. 2374-2375.
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