An active, selective, and stable manganese oxide-supported atomic Pd catalyst for aerobic oxidation of 5-hydroxymethylfurfural

Xuemei Liao, Jindou Hou, Ya Wang, Hao Zhang, Yu Sun, Xiaopeng Li, Siyang Tang, Kenichi Kato, Miho Yamauchi, Zheng Jiang

Research output: Contribution to journalArticle

Abstract

Here we report for the first time a Pd-MnO2 catalyst with a single-atom feature that can convert 5-hydroxylmethyfurfural (HMF) into the important bioplastic building block 2,5-furandicarboxylic acid (FDCA) with a high yield of 88% in aqueous solution using O2 as an oxidant at ambient pressure. Pd-MnO2 shows higher activity in the productivity of FDCA (100.91 mmol h-1 gPd-1) than its Pd nanoparticle counterpart (45.57 mmol h-1 gPd-1) and state-of-the-art Pd-based catalysts. Pd-MnO2 displays promising recyclability with no degradation after five catalytic runs. Experimental and theoretical results suggest that the single-atom Pd sites that have enhanced binding affinity to HMF and their surrounding sites on the MnO2 support work synergistically toward HMF oxidation.

Original languageEnglish
Pages (from-to)4194-4203
Number of pages10
JournalGreen Chemistry
Volume21
Issue number15
DOIs
Publication statusPublished - Jan 1 2019

Fingerprint

Manganese oxide
manganese oxide
catalyst
oxidation
Atoms
Oxidation
Catalysts
Acids
acid
Oxidants
oxidant
aqueous solution
Productivity
Nanoparticles
Degradation
productivity
degradation
5-hydroxymethylfurfural
nanoparticle
state of the art

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Pollution

Cite this

An active, selective, and stable manganese oxide-supported atomic Pd catalyst for aerobic oxidation of 5-hydroxymethylfurfural. / Liao, Xuemei; Hou, Jindou; Wang, Ya; Zhang, Hao; Sun, Yu; Li, Xiaopeng; Tang, Siyang; Kato, Kenichi; Yamauchi, Miho; Jiang, Zheng.

In: Green Chemistry, Vol. 21, No. 15, 01.01.2019, p. 4194-4203.

Research output: Contribution to journalArticle

Liao, Xuemei ; Hou, Jindou ; Wang, Ya ; Zhang, Hao ; Sun, Yu ; Li, Xiaopeng ; Tang, Siyang ; Kato, Kenichi ; Yamauchi, Miho ; Jiang, Zheng. / An active, selective, and stable manganese oxide-supported atomic Pd catalyst for aerobic oxidation of 5-hydroxymethylfurfural. In: Green Chemistry. 2019 ; Vol. 21, No. 15. pp. 4194-4203.
@article{3c6084cf94164db2990a622d9664fe36,
title = "An active, selective, and stable manganese oxide-supported atomic Pd catalyst for aerobic oxidation of 5-hydroxymethylfurfural",
abstract = "Here we report for the first time a Pd-MnO2 catalyst with a single-atom feature that can convert 5-hydroxylmethyfurfural (HMF) into the important bioplastic building block 2,5-furandicarboxylic acid (FDCA) with a high yield of 88{\%} in aqueous solution using O2 as an oxidant at ambient pressure. Pd-MnO2 shows higher activity in the productivity of FDCA (100.91 mmol h-1 gPd-1) than its Pd nanoparticle counterpart (45.57 mmol h-1 gPd-1) and state-of-the-art Pd-based catalysts. Pd-MnO2 displays promising recyclability with no degradation after five catalytic runs. Experimental and theoretical results suggest that the single-atom Pd sites that have enhanced binding affinity to HMF and their surrounding sites on the MnO2 support work synergistically toward HMF oxidation.",
author = "Xuemei Liao and Jindou Hou and Ya Wang and Hao Zhang and Yu Sun and Xiaopeng Li and Siyang Tang and Kenichi Kato and Miho Yamauchi and Zheng Jiang",
year = "2019",
month = "1",
day = "1",
doi = "10.1039/c9gc01674k",
language = "English",
volume = "21",
pages = "4194--4203",
journal = "Green Chemistry",
issn = "1463-9262",
publisher = "Royal Society of Chemistry",
number = "15",

}

TY - JOUR

T1 - An active, selective, and stable manganese oxide-supported atomic Pd catalyst for aerobic oxidation of 5-hydroxymethylfurfural

AU - Liao, Xuemei

AU - Hou, Jindou

AU - Wang, Ya

AU - Zhang, Hao

AU - Sun, Yu

AU - Li, Xiaopeng

AU - Tang, Siyang

AU - Kato, Kenichi

AU - Yamauchi, Miho

AU - Jiang, Zheng

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Here we report for the first time a Pd-MnO2 catalyst with a single-atom feature that can convert 5-hydroxylmethyfurfural (HMF) into the important bioplastic building block 2,5-furandicarboxylic acid (FDCA) with a high yield of 88% in aqueous solution using O2 as an oxidant at ambient pressure. Pd-MnO2 shows higher activity in the productivity of FDCA (100.91 mmol h-1 gPd-1) than its Pd nanoparticle counterpart (45.57 mmol h-1 gPd-1) and state-of-the-art Pd-based catalysts. Pd-MnO2 displays promising recyclability with no degradation after five catalytic runs. Experimental and theoretical results suggest that the single-atom Pd sites that have enhanced binding affinity to HMF and their surrounding sites on the MnO2 support work synergistically toward HMF oxidation.

AB - Here we report for the first time a Pd-MnO2 catalyst with a single-atom feature that can convert 5-hydroxylmethyfurfural (HMF) into the important bioplastic building block 2,5-furandicarboxylic acid (FDCA) with a high yield of 88% in aqueous solution using O2 as an oxidant at ambient pressure. Pd-MnO2 shows higher activity in the productivity of FDCA (100.91 mmol h-1 gPd-1) than its Pd nanoparticle counterpart (45.57 mmol h-1 gPd-1) and state-of-the-art Pd-based catalysts. Pd-MnO2 displays promising recyclability with no degradation after five catalytic runs. Experimental and theoretical results suggest that the single-atom Pd sites that have enhanced binding affinity to HMF and their surrounding sites on the MnO2 support work synergistically toward HMF oxidation.

UR - http://www.scopus.com/inward/record.url?scp=85070332834&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85070332834&partnerID=8YFLogxK

U2 - 10.1039/c9gc01674k

DO - 10.1039/c9gc01674k

M3 - Article

AN - SCOPUS:85070332834

VL - 21

SP - 4194

EP - 4203

JO - Green Chemistry

JF - Green Chemistry

SN - 1463-9262

IS - 15

ER -