An Azulene-Fused Tetracene Diimide with a Small HOMO–LUMO Gap

Taro Koide, Moritaka Takesue, Toshihiro Murafuji, Koichiro Satomi, Yasutaka Suzuki, Jun Kawamata, Kengo Terai, Mitsuharu Suzuki, Hiroko Yamada, Yoshihito Shiota, Kazunari Yoshizawa, Fumito Tani

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

A newly prepared tetraazulene-fused tetracene diimide (TA-fused TDI) showed absorption in the near-IR region owing to the effective extension of the π-conjugated system as well as a large two-photon absorption cross-section (σ(2)=2140 GM) at 950 nm. Four reversible reduction processes and n-type semiconductivity were also confirmed as attractive electronic properties of this compound.

Original languageEnglish
Pages (from-to)1010-1014
Number of pages5
JournalChemPlusChem
Volume82
Issue number7
DOIs
Publication statusPublished - Aug 1 2017

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Electronic properties
Photons
azulene
naphthacene

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Koide, T., Takesue, M., Murafuji, T., Satomi, K., Suzuki, Y., Kawamata, J., ... Tani, F. (2017). An Azulene-Fused Tetracene Diimide with a Small HOMO–LUMO Gap. ChemPlusChem, 82(7), 1010-1014. https://doi.org/10.1002/cplu.201600356

An Azulene-Fused Tetracene Diimide with a Small HOMO–LUMO Gap. / Koide, Taro; Takesue, Moritaka; Murafuji, Toshihiro; Satomi, Koichiro; Suzuki, Yasutaka; Kawamata, Jun; Terai, Kengo; Suzuki, Mitsuharu; Yamada, Hiroko; Shiota, Yoshihito; Yoshizawa, Kazunari; Tani, Fumito.

In: ChemPlusChem, Vol. 82, No. 7, 01.08.2017, p. 1010-1014.

Research output: Contribution to journalArticle

Koide, T, Takesue, M, Murafuji, T, Satomi, K, Suzuki, Y, Kawamata, J, Terai, K, Suzuki, M, Yamada, H, Shiota, Y, Yoshizawa, K & Tani, F 2017, 'An Azulene-Fused Tetracene Diimide with a Small HOMO–LUMO Gap', ChemPlusChem, vol. 82, no. 7, pp. 1010-1014. https://doi.org/10.1002/cplu.201600356
Koide T, Takesue M, Murafuji T, Satomi K, Suzuki Y, Kawamata J et al. An Azulene-Fused Tetracene Diimide with a Small HOMO–LUMO Gap. ChemPlusChem. 2017 Aug 1;82(7):1010-1014. https://doi.org/10.1002/cplu.201600356
Koide, Taro ; Takesue, Moritaka ; Murafuji, Toshihiro ; Satomi, Koichiro ; Suzuki, Yasutaka ; Kawamata, Jun ; Terai, Kengo ; Suzuki, Mitsuharu ; Yamada, Hiroko ; Shiota, Yoshihito ; Yoshizawa, Kazunari ; Tani, Fumito. / An Azulene-Fused Tetracene Diimide with a Small HOMO–LUMO Gap. In: ChemPlusChem. 2017 ; Vol. 82, No. 7. pp. 1010-1014.
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