An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes: Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium(II/III)-Based Electrochromism

Masaaki Abe; Hiroki Futagawa; Toshikazu Ono; Teppei Yamada; Nobuo Kimizuka; Yoshio Hisaeda

doi:10.1021/acs.inorgchem.5b02129

An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes: Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium(II/III)-Based Electrochromism

Masaaki Abe, Hiroki Futagawa, Toshikazu Ono, Teppei Yamada, Nobuo Kimizuka, Yoshio Hisaeda

Research output: Contribution to journal › Article

22 Citations (Scopus)

Abstract

Oxidative electropolymeization of an axially bound, bithiophene-pyridine complex of ruthenium(III)-porphycene [Ru(TPrPc) (btp)₂]PF₆ (1) gives a submicrometer-thick, polymeric film on an ITO electrode with a crystalline morphology. The polymeric film, the first example of axially linked multimetalloporphycene coordination arrays, exhibits highly stable and reproducible electrochromic response with high electrochromic efficiency upon electrochemical control over the metal-centered electron transfer process (Ru^II/Ru^III).

Original language	English
Pages (from-to)	11061-11063
Number of pages	3
Journal	Inorganic Chemistry
Volume	54
Issue number	23
DOIs	https://doi.org/10.1021/acs.inorgchem.5b02129
Publication status	Published - Nov 16 2015

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes : Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium(II/III)-Based Electrochromism. / Abe, Masaaki; Futagawa, Hiroki; Ono, Toshikazu ; Yamada, Teppei ; Kimizuka, Nobuo ; Hisaeda, Yoshio.

In: Inorganic Chemistry, Vol. 54, No. 23, 16.11.2015, p. 11061-11063.

Research output: Contribution to journal › Article

Abe, M, Futagawa, H, Ono, T , Yamada, T , Kimizuka, N & Hisaeda, Y 2015, 'An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes: Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium(II/III)-Based Electrochromism', Inorganic Chemistry, vol. 54, no. 23, pp. 11061-11063. https://doi.org/10.1021/acs.inorgchem.5b02129

Abe, Masaaki ; Futagawa, Hiroki ; Ono, Toshikazu ; Yamada, Teppei ; Kimizuka, Nobuo ; Hisaeda, Yoshio. / An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes : Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium(II/III)-Based Electrochromism. In: Inorganic Chemistry. 2015 ; Vol. 54, No. 23. pp. 11061-11063.

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