TY - JOUR
T1 - An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes
T2 - Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium(II/III)-Based Electrochromism
AU - Abe, Masaaki
AU - Futagawa, Hiroki
AU - Ono, Toshikazu
AU - Yamada, Teppei
AU - Kimizuka, Nobuo
AU - Hisaeda, Yoshio
N1 - Publisher Copyright:
© 2015 American Chemical Society.
Copyright:
Copyright 2015 Elsevier B.V., All rights reserved.
PY - 2015/11/16
Y1 - 2015/11/16
N2 - Oxidative electropolymeization of an axially bound, bithiophene-pyridine complex of ruthenium(III)-porphycene [Ru(TPrPc) (btp)2]PF6 (1) gives a submicrometer-thick, polymeric film on an ITO electrode with a crystalline morphology. The polymeric film, the first example of axially linked multimetalloporphycene coordination arrays, exhibits highly stable and reproducible electrochromic response with high electrochromic efficiency upon electrochemical control over the metal-centered electron transfer process (RuII/RuIII).
AB - Oxidative electropolymeization of an axially bound, bithiophene-pyridine complex of ruthenium(III)-porphycene [Ru(TPrPc) (btp)2]PF6 (1) gives a submicrometer-thick, polymeric film on an ITO electrode with a crystalline morphology. The polymeric film, the first example of axially linked multimetalloporphycene coordination arrays, exhibits highly stable and reproducible electrochromic response with high electrochromic efficiency upon electrochemical control over the metal-centered electron transfer process (RuII/RuIII).
UR - http://www.scopus.com/inward/record.url?scp=84949438473&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84949438473&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.5b02129
DO - 10.1021/acs.inorgchem.5b02129
M3 - Article
AN - SCOPUS:84949438473
VL - 54
SP - 11061
EP - 11063
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 23
ER -