An enantiocontrolled total synthesis of (-)-xanthorrhizol

Kenji Sato; Toshikazu Bando; Mitsuru Shindo; Kozo Shishido

doi:10.3987/com-98-s(h)4

An enantiocontrolled total synthesis of (-)-xanthorrhizol

Kenji Sato, Toshikazu Bando, Mitsuru Shindo, Kozo Shishido

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

An efficient and enantiocontrolled total synthesis of natural (-)- xanthorrhizol (3) has been accomplished by employing the lipase-mediated asymmetric acetylation of the σ-symmetrical prochiral 2-aryl-1,3-propanediol (7) leading to the formation of the optically enriched monoacetate (6) as the key step.

Original language	English
Pages (from-to)	11-15
Number of pages	5
Journal	Heterocycles
Volume	50
Issue number	1
DOIs	https://doi.org/10.3987/com-98-s(h)4
Publication status	Published - Jan 1 1999
Externally published	Yes

All Science Journal Classification (ASJC) codes

Analytical Chemistry
Pharmacology
Organic Chemistry

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10.3987/com-98-s(h)4

Cite this

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abstract = "An efficient and enantiocontrolled total synthesis of natural (-)- xanthorrhizol (3) has been accomplished by employing the lipase-mediated asymmetric acetylation of the σ-symmetrical prochiral 2-aryl-1,3-propanediol (7) leading to the formation of the optically enriched monoacetate (6) as the key step.",

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AU - Shishido, Kozo

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N2 - An efficient and enantiocontrolled total synthesis of natural (-)- xanthorrhizol (3) has been accomplished by employing the lipase-mediated asymmetric acetylation of the σ-symmetrical prochiral 2-aryl-1,3-propanediol (7) leading to the formation of the optically enriched monoacetate (6) as the key step.

AB - An efficient and enantiocontrolled total synthesis of natural (-)- xanthorrhizol (3) has been accomplished by employing the lipase-mediated asymmetric acetylation of the σ-symmetrical prochiral 2-aryl-1,3-propanediol (7) leading to the formation of the optically enriched monoacetate (6) as the key step.

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An enantiocontrolled total synthesis of (-)-xanthorrhizol

Abstract

All Science Journal Classification (ASJC) codes

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