An integral equation study of reentrant behavior in attractive interactions between like-charged macroions immersed in an electrolyte solution

Ryo Akiyama, Ryo Sakata

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13 Citations (Scopus)

Abstract

The effective interaction between two like-charged macroions immersed in an electrolyte solution was studied using a Ornstein-Zernike equation with hypernetted-chain closure (HNC-OZ theory) with a particle model for the ions and solvent molecules to discuss some biological phenomena. We examined conditions under which the Coulomb interaction was greater than the thermal energy. Although the macroions repelled each other in a dilute electrolyte solution, a strong effective attraction between macroions occurred only in a medium concentration electrolyte. The effective interaction is analyzed using the superposition approximation to discuss the bond formation. When the effective attraction appears, the dense cloud of countercharged ion exists between the macroions and the cloud mediates the attraction like a covalent bond.

Original languageEnglish
Article number123602
Journaljournal of the physical society of japan
Volume80
Issue number12
DOIs
Publication statusPublished - Dec 1 2011

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attraction
integral equations
electrolytes
covalent bonds
interactions
thermal energy
closures
ions
approximation
molecules

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

Cite this

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