An ion‐gate response of a glutathione monolayer assembly highly sensitive to lanthanide ions

Kô Takehara; Makoto Aihara; Nami Ueda

doi:10.1002/elan.1140061128

An ion‐gate response of a glutathione monolayer assembly highly sensitive to lanthanide ions

Kô Takehara, Makoto Aihara, Nami Ueda

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The self‐assembled glutathione (γ‐L‐glutamyl‐L‐cysteinyl‐glycine, GSH) monolayer was formed on a gold electrode via a sulfur attachment of the cysteinyl residue. The effect of lanthanide ions (La³⁺, Eu³⁺ and Lu³⁺) on the ion‐gate behavior of this electrode was studied by using cyclic voltammetry (CV) and Fe(CN)₆^3– as a probe ion. These ions were found to open the ion gate with a few micromoles, and the effect was in the order of La³⁺ > Eu³⁺ Lu³⁺.

Original language	English
Pages (from-to)	1083-1086
Number of pages	4
Journal	Electroanalysis
Volume	6
Issue number	11-12
DOIs	https://doi.org/10.1002/elan.1140061128
Publication status	Published - Jan 1 1994

All Science Journal Classification (ASJC) codes

Analytical Chemistry
Electrochemistry

Access to Document

10.1002/elan.1140061128

Cite this

@article{3a9725bf646042b4aa5a2762ef79cd8b,

title = "An ion‐gate response of a glutathione monolayer assembly highly sensitive to lanthanide ions",

abstract = "The self‐assembled glutathione (γ‐L‐glutamyl‐L‐cysteinyl‐glycine, GSH) monolayer was formed on a gold electrode via a sulfur attachment of the cysteinyl residue. The effect of lanthanide ions (La3+, Eu3+ and Lu3+) on the ion‐gate behavior of this electrode was studied by using cyclic voltammetry (CV) and Fe(CN)63– as a probe ion. These ions were found to open the ion gate with a few micromoles, and the effect was in the order of La3+ > Eu3+ Lu3+.",

author = "K{\^o} Takehara and Makoto Aihara and Nami Ueda",

year = "1994",

month = jan,

day = "1",

doi = "10.1002/elan.1140061128",

language = "English",

volume = "6",

pages = "1083--1086",

journal = "Electroanalysis",

issn = "1040-0397",

publisher = "Wiley-VCH Verlag",

number = "11-12",

}

TY - JOUR

T1 - An ion‐gate response of a glutathione monolayer assembly highly sensitive to lanthanide ions

AU - Takehara, Kô

AU - Aihara, Makoto

AU - Ueda, Nami

PY - 1994/1/1

Y1 - 1994/1/1

N2 - The self‐assembled glutathione (γ‐L‐glutamyl‐L‐cysteinyl‐glycine, GSH) monolayer was formed on a gold electrode via a sulfur attachment of the cysteinyl residue. The effect of lanthanide ions (La3+, Eu3+ and Lu3+) on the ion‐gate behavior of this electrode was studied by using cyclic voltammetry (CV) and Fe(CN)63– as a probe ion. These ions were found to open the ion gate with a few micromoles, and the effect was in the order of La3+ > Eu3+ Lu3+.

AB - The self‐assembled glutathione (γ‐L‐glutamyl‐L‐cysteinyl‐glycine, GSH) monolayer was formed on a gold electrode via a sulfur attachment of the cysteinyl residue. The effect of lanthanide ions (La3+, Eu3+ and Lu3+) on the ion‐gate behavior of this electrode was studied by using cyclic voltammetry (CV) and Fe(CN)63– as a probe ion. These ions were found to open the ion gate with a few micromoles, and the effect was in the order of La3+ > Eu3+ Lu3+.

UR - http://www.scopus.com/inward/record.url?scp=84987471871&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84987471871&partnerID=8YFLogxK

U2 - 10.1002/elan.1140061128

DO - 10.1002/elan.1140061128

M3 - Article

AN - SCOPUS:84987471871

SN - 1040-0397

VL - 6

SP - 1083

EP - 1086

JO - Electroanalysis

JF - Electroanalysis

IS - 11-12

ER -

An ion‐gate response of a glutathione monolayer assembly highly sensitive to lanthanide ions

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this