An oxygen-sensitive luminescent Dy(III) complex

Hidetaka Nakai, Juncheol Seo, Kazuhiro Kitagawa, Takahiro Goto, Takahiro Matsumoto, Seiji Ogo

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    9 Citations (Scopus)

    Abstract

    This paper presents the first dysprosium(iii) complex, [{(MeMeArO)3tacn}DyIII(THF)] (1Dy), that shows oxygen-sensitive luminescence. The synthesis, structure and oxygen-sensitive luminescence properties of 1Dy are reported (Φ = 0.050 and τ = 17.7 μs under N2, Φ = 0.011 and τ = 4.1 μs under O2 and KSV = 305 M-1 in THF; KSV = 0.0077%-1 in polystyrene film). The oxygen sensitive mechanism of 1Dy is discussed based on the photophysical properties of the corresponding gadolinium(iii) complex, [{(MeMeArO)3tacn}GdIII(THF)].

    Original languageEnglish
    Pages (from-to)9492-9496
    Number of pages5
    JournalDalton Transactions
    Volume45
    Issue number23
    DOIs
    Publication statusPublished - 2016

    All Science Journal Classification (ASJC) codes

    • Inorganic Chemistry

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