An oxygen-sensitive luminescent Dy(III) complex

Hidetaka Nakai, Juncheol Seo, Kazuhiro Kitagawa, Takahiro Goto, Takahiro Matsumoto, Seiji Ogo

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

This paper presents the first dysprosium(iii) complex, [{(MeMeArO)3tacn}DyIII(THF)] (1Dy), that shows oxygen-sensitive luminescence. The synthesis, structure and oxygen-sensitive luminescence properties of 1Dy are reported (Φ = 0.050 and τ = 17.7 μs under N2, Φ = 0.011 and τ = 4.1 μs under O2 and KSV = 305 M-1 in THF; KSV = 0.0077%-1 in polystyrene film). The oxygen sensitive mechanism of 1Dy is discussed based on the photophysical properties of the corresponding gadolinium(iii) complex, [{(MeMeArO)3tacn}GdIII(THF)].

Original languageEnglish
Pages (from-to)9492-9496
Number of pages5
JournalDalton Transactions
Volume45
Issue number23
DOIs
Publication statusPublished - Jan 1 2016

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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