TY - JOUR
T1 - An unprecedented ten-connected 3D metal-organic framework based on hexanuclear cobalt(II) cluster building blocks
AU - Guo, Zhiyong
AU - Su, Shengqun
AU - Deng, Ruiping
AU - Zhang, Hongjie
N1 - Funding Information:
The authors are grateful to the financial aid from the National Natural Science Foundation of China (Grant Nos. 21371165 , 51372242 , 91122030 and 21210001 ), and National Natural Science Foundation for Creative Research Group (Grant No. 21221061 ).
Publisher Copyright:
© 2014 Elsevier B.V.
PY - 2015/1
Y1 - 2015/1
N2 - A 3D metal-organic framework (MOF), [Co3(μ3-OH)(μ2-H2O)(BPT)(HBPT)(DMF)2](DMF)(H2O) (1) (DMF = N, N′-dimethylformamide) has been synthesized by self-assembly of cobalt(II) oxide and biphenyl-3, 4′, 5-tricarboxylate (H3BPT) under solvothermal reaction. Compound 1 displays unique (2,3,10)-connected trinodal connected topology. Besides, 1 represents a rare example of MOF possessing free carboxylic acids. In addition, the magnetic property of the compound is investigated.
AB - A 3D metal-organic framework (MOF), [Co3(μ3-OH)(μ2-H2O)(BPT)(HBPT)(DMF)2](DMF)(H2O) (1) (DMF = N, N′-dimethylformamide) has been synthesized by self-assembly of cobalt(II) oxide and biphenyl-3, 4′, 5-tricarboxylate (H3BPT) under solvothermal reaction. Compound 1 displays unique (2,3,10)-connected trinodal connected topology. Besides, 1 represents a rare example of MOF possessing free carboxylic acids. In addition, the magnetic property of the compound is investigated.
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U2 - 10.1016/j.inoche.2014.10.030
DO - 10.1016/j.inoche.2014.10.030
M3 - Article
AN - SCOPUS:84910044424
SN - 1387-7003
VL - 51
SP - 9
EP - 12
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
ER -