An unprecedented ten-connected 3D metal-organic framework based on hexanuclear cobalt(II) cluster building blocks

Zhiyong Guo, Shengqun Su, Ruiping Deng, Hongjie Zhang

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

A 3D metal-organic framework (MOF), [Co33-OH)(μ2-H2O)(BPT)(HBPT)(DMF)2](DMF)(H2O) (1) (DMF = N, N′-dimethylformamide) has been synthesized by self-assembly of cobalt(II) oxide and biphenyl-3, 4′, 5-tricarboxylate (H3BPT) under solvothermal reaction. Compound 1 displays unique (2,3,10)-connected trinodal connected topology. Besides, 1 represents a rare example of MOF possessing free carboxylic acids. In addition, the magnetic property of the compound is investigated.

Original languageEnglish
Pages (from-to)9-12
Number of pages4
JournalInorganic Chemistry Communications
Volume51
DOIs
Publication statusPublished - Jan 2015
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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