An ynolate-initiated tandem process giving cyclopentenones: Total synthesis of cucumin E

Mitsuru Shindo; Yusuke Sato; Kozo Shishido

doi:10.1016/S0040-4039(02)01015-8

An ynolate-initiated tandem process giving cyclopentenones: Total synthesis of cucumin E

Mitsuru Shindo, Yusuke Sato, Kozo Shishido

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

A total synthesis of cucumin E, a novel type of triquinane natural product, has been accomplished. The strategy is based on an ynolate-initiated tandem [2+2] cycloaddition-Dieckmann condensation, followed by decarboxylation, giving cyclopentenones.

Original language	English
Pages (from-to)	5039-5041
Number of pages	3
Journal	Tetrahedron Letters
Volume	43
Issue number	29
DOIs	https://doi.org/10.1016/S0040-4039(02)01015-8
Publication status	Published - Jul 15 2002
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(02)01015-8

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title = "An ynolate-initiated tandem process giving cyclopentenones: Total synthesis of cucumin E",

abstract = "A total synthesis of cucumin E, a novel type of triquinane natural product, has been accomplished. The strategy is based on an ynolate-initiated tandem [2+2] cycloaddition-Dieckmann condensation, followed by decarboxylation, giving cyclopentenones.",

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AU - Shishido, Kozo

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AB - A total synthesis of cucumin E, a novel type of triquinane natural product, has been accomplished. The strategy is based on an ynolate-initiated tandem [2+2] cycloaddition-Dieckmann condensation, followed by decarboxylation, giving cyclopentenones.

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