Analysis of the anodic reaction mechanism for solid oxide fuel cell using BaCeO3 electrolyte

Michihisa Koyama, Ching Ju Wen, Junichiro Otomo, Noboru Taniguchi, Koichi Yamada, Koichi Eguchi, Hiroshi Takahashi, Hiroshi Komiyama

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4 Citations (Scopus)

Abstract

BaCeO3, one of the candidate materials for solid oxide fuel cell electrolyte, is a H+/O2- mixed ionic conductor. In this study, we measured AC impedance of the anode with the O2-, H- and O2-, or H+ as ionic charge carrier in the electrolyte. The measured impedance was analyzed by using the equivalent circuit, and the anodic reaction mechanism was analyzed by comparing the results and abstracted information in each system, in order to clarify the elementary reaction processes dominating the anodic reaction. The anodic reaction for H-/O2- mixed ionic conductor electrolyte is more complex than that for electrolytes with a single ionic charge carrier. Therefore, designing an electrode with lower over-potential requires the several elementary processes involved to be accelerated at the same time. A guideline for design of a lower overpotential electrode was proposed based on the knowledge acquired so far.

Original languageEnglish
Pages (from-to)214-220
Number of pages7
Journalkagaku kogaku ronbunshu
Volume29
Issue number2
DOIs
Publication statusPublished - Mar 2003

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

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    Koyama, M., Wen, C. J., Otomo, J., Taniguchi, N., Yamada, K., Eguchi, K., Takahashi, H., & Komiyama, H. (2003). Analysis of the anodic reaction mechanism for solid oxide fuel cell using BaCeO3 electrolyte. kagaku kogaku ronbunshu, 29(2), 214-220. https://doi.org/10.1252/kakoronbunshu.29.214