Anionic copolymerization of 2,3,4,5,6‐pentafluorostyrene and divinylbenzene

Shin Nishimura, Akira Nagai, Akio Takahashi, Tadashi Narita

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Anionic copolymerizations of 2,3,4,5,6‐pentafluorostyrene (PFS) with 1,3‐divinylbenzene (m‐DVB) and 1,4‐divinylbenzene (p‐DVB) were performed by using lithium diisopropylamide as an initiator in order to synthesize the fluorine‐containing linear polymer with pendant vinyl groups. The products were soluble copolymers possessing both PFS and DVB monomeric units, and the DVB monomeric unit in copolymer had pendant vinyl group. This copolymerization reaction took a much longer time than that of styrene with DVB. The copolymerization parameter of this system was examined from copolymer composition curves. In this system, m‐DVB was found to be more reactive than p‐DVB. The reactivity of copolymerization was largely influenced by the reactivity of active species. © 1993 John Wiley & Sons, Inc.

Original languageEnglish
Pages (from-to)135-139
Number of pages5
JournalJournal of Polymer Science Part A: Polymer Chemistry
Volume31
Issue number1
DOIs
Publication statusPublished - Jan 1 1993

Fingerprint

divinyl benzene
Copolymerization
Copolymers
Styrene
Polymers
Lithium
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Organic Chemistry
  • Materials Chemistry

Cite this

Anionic copolymerization of 2,3,4,5,6‐pentafluorostyrene and divinylbenzene. / Nishimura, Shin; Nagai, Akira; Takahashi, Akio; Narita, Tadashi.

In: Journal of Polymer Science Part A: Polymer Chemistry, Vol. 31, No. 1, 01.01.1993, p. 135-139.

Research output: Contribution to journalArticle

Nishimura, Shin ; Nagai, Akira ; Takahashi, Akio ; Narita, Tadashi. / Anionic copolymerization of 2,3,4,5,6‐pentafluorostyrene and divinylbenzene. In: Journal of Polymer Science Part A: Polymer Chemistry. 1993 ; Vol. 31, No. 1. pp. 135-139.
@article{807801c2fbd547279e0b6ca79f82e591,
title = "Anionic copolymerization of 2,3,4,5,6‐pentafluorostyrene and divinylbenzene",
abstract = "Anionic copolymerizations of 2,3,4,5,6‐pentafluorostyrene (PFS) with 1,3‐divinylbenzene (m‐DVB) and 1,4‐divinylbenzene (p‐DVB) were performed by using lithium diisopropylamide as an initiator in order to synthesize the fluorine‐containing linear polymer with pendant vinyl groups. The products were soluble copolymers possessing both PFS and DVB monomeric units, and the DVB monomeric unit in copolymer had pendant vinyl group. This copolymerization reaction took a much longer time than that of styrene with DVB. The copolymerization parameter of this system was examined from copolymer composition curves. In this system, m‐DVB was found to be more reactive than p‐DVB. The reactivity of copolymerization was largely influenced by the reactivity of active species. {\circledC} 1993 John Wiley & Sons, Inc.",
author = "Shin Nishimura and Akira Nagai and Akio Takahashi and Tadashi Narita",
year = "1993",
month = "1",
day = "1",
doi = "10.1002/pola.1993.080310116",
language = "English",
volume = "31",
pages = "135--139",
journal = "Journal of Polymer Science, Part A: Polymer Chemistry",
issn = "0887-624X",
publisher = "John Wiley and Sons Inc.",
number = "1",

}

TY - JOUR

T1 - Anionic copolymerization of 2,3,4,5,6‐pentafluorostyrene and divinylbenzene

AU - Nishimura, Shin

AU - Nagai, Akira

AU - Takahashi, Akio

AU - Narita, Tadashi

PY - 1993/1/1

Y1 - 1993/1/1

N2 - Anionic copolymerizations of 2,3,4,5,6‐pentafluorostyrene (PFS) with 1,3‐divinylbenzene (m‐DVB) and 1,4‐divinylbenzene (p‐DVB) were performed by using lithium diisopropylamide as an initiator in order to synthesize the fluorine‐containing linear polymer with pendant vinyl groups. The products were soluble copolymers possessing both PFS and DVB monomeric units, and the DVB monomeric unit in copolymer had pendant vinyl group. This copolymerization reaction took a much longer time than that of styrene with DVB. The copolymerization parameter of this system was examined from copolymer composition curves. In this system, m‐DVB was found to be more reactive than p‐DVB. The reactivity of copolymerization was largely influenced by the reactivity of active species. © 1993 John Wiley & Sons, Inc.

AB - Anionic copolymerizations of 2,3,4,5,6‐pentafluorostyrene (PFS) with 1,3‐divinylbenzene (m‐DVB) and 1,4‐divinylbenzene (p‐DVB) were performed by using lithium diisopropylamide as an initiator in order to synthesize the fluorine‐containing linear polymer with pendant vinyl groups. The products were soluble copolymers possessing both PFS and DVB monomeric units, and the DVB monomeric unit in copolymer had pendant vinyl group. This copolymerization reaction took a much longer time than that of styrene with DVB. The copolymerization parameter of this system was examined from copolymer composition curves. In this system, m‐DVB was found to be more reactive than p‐DVB. The reactivity of copolymerization was largely influenced by the reactivity of active species. © 1993 John Wiley & Sons, Inc.

UR - http://www.scopus.com/inward/record.url?scp=0027150203&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0027150203&partnerID=8YFLogxK

U2 - 10.1002/pola.1993.080310116

DO - 10.1002/pola.1993.080310116

M3 - Article

VL - 31

SP - 135

EP - 139

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

SN - 0887-624X

IS - 1

ER -