Anionic polymerization of methacrylate-functionalized ionic monomers in ionic liquid

Nobuyuki Otozawa, Masataka Yoshioka, Daiki Ihara, Rio Hamajima, Raito Kato, Toshiki Terao, Hiroto Fukuma, Satoshi Kuretani, Tamio Seko, Syuji Fujii, Yoshinobu Nakamura, Motoyasu Kobayashi, Atsushi Takahara, Tomoyasu Hirai

Research output: Contribution to journalArticlepeer-review

Abstract

Anionic polymerization of methacrylate-functionalized ionic monomers, 2-(methacryloyloxy)ethyltrimethylammonium chloride (MTAC) and 3-(N-2-methacryloyloxyethyl-N,N-dimethyl)-ammonatopropanesulfonate (MAPS), was performed using conventional alkyl lithium as an initiator in ionic liquid, leading to poly(MTAC) (PMTAC) and poly(MAPS) (PMAPS). During an anionic polymerization, ionic liquid acts as solvent and additive. The dual role of ionic liquid gives PMAPS heterotactic configuration.

Original languageEnglish
Pages (from-to)1459-1461
Number of pages3
JournalChemistry Letters
Volume49
Issue number12
DOIs
Publication statusPublished - 2020

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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