Anisotropy of thermal diffusivity in lead halide perovskite layers revealed by thermal grating technique

P. Ščajev, R. Aleksieju Nas, S. Terakawa, C. Qin, T. Fujihara, Toshinori Matsusima, Chihaya Adachi, S. Juršenas

Research output: Contribution to journalArticle

Abstract

Heat management of optoelectronic devices is of critical significance in lead halide perovskites due to the intrinsically low thermal conductivity of this material. Despite its importance, thermal conductivity remains understudied, particularly in polycrystalline perovskite layers with different halides. Here, we employ a novel method for investigation of thermal properties in perovskite layers, which is based on a light-induced transient diffraction grating technique. We demonstrate the applicability of thermal grating technique by determining in an all-optical way the thermo-optic coefficient, speed of sound, and thermal conductivity in vapor-deposited polycrystalline layers of MAPbX3 (X = Cl, Br, I), MAPbBr2I, and MAPbCl2Br perovskites. We reveal the spatial anisotropy of thermal conductivity, which is noticeably lower in the direction along the layer surface (0.2-0.5 W/(m K)) if compared to that across the layer (0.3-1.1 W/(m K)). Finally, we demonstrate that for both directions the thermal conductivity scales linearly with the average speed of sound in the perovskite layers.

Original languageEnglish
Pages (from-to)14914-14920
Number of pages7
JournalJournal of Physical Chemistry C
Volume123
Issue number24
DOIs
Publication statusPublished - Jun 20 2019

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Thermal diffusivity
thermal diffusivity
Perovskite
halides
Thermal conductivity
Anisotropy
thermal conductivity
Lead
gratings
anisotropy
Acoustic wave velocity
perovskites
acoustics
Diffraction gratings
gratings (spectra)
optoelectronic devices
Optoelectronic devices
Optics
surface layers
Thermodynamic properties

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Anisotropy of thermal diffusivity in lead halide perovskite layers revealed by thermal grating technique. / Ščajev, P.; Aleksieju Nas, R.; Terakawa, S.; Qin, C.; Fujihara, T.; Matsusima, Toshinori; Adachi, Chihaya; Juršenas, S.

In: Journal of Physical Chemistry C, Vol. 123, No. 24, 20.06.2019, p. 14914-14920.

Research output: Contribution to journalArticle

Ščajev, P. ; Aleksieju Nas, R. ; Terakawa, S. ; Qin, C. ; Fujihara, T. ; Matsusima, Toshinori ; Adachi, Chihaya ; Juršenas, S. / Anisotropy of thermal diffusivity in lead halide perovskite layers revealed by thermal grating technique. In: Journal of Physical Chemistry C. 2019 ; Vol. 123, No. 24. pp. 14914-14920.
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AU - Fujihara, T.

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